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Volumn 29, Issue 11, 1996, Pages 4158-4160

Macroporous epoxy networks via chemically induced phase separation

Author keywords

[No Author keywords available]

Indexed keywords

CROSSLINKING; CURING; DECOMPOSITION; FOAMED PLASTICS; MOLECULAR WEIGHT; MORPHOLOGY; PHASE SEPARATION; POROSITY; SOLUBILITY; SOLVENTS; SYNTHESIS (CHEMICAL); THERMOGRAVIMETRIC ANALYSIS;

EID: 0030143658     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma951674a     Document Type: Article
Times cited : (35)

References (25)
  • 3
    • 0003551358 scopus 로고
    • Advances in Chemistry 114
    • American Chemical Society: Washington, DC
    • Bauer, R. S. Epoxy Resin Chemistry; Advances in Chemistry 114; American Chemical Society: Washington, DC, 1979.
    • (1979) Epoxy Resin Chemistry
    • Bauer, R.S.1
  • 7
    • 0003803780 scopus 로고
    • Advances in Chemistry 208
    • American Chemical Society: Washington, DC
    • Riew, C. K.; Gillham, J. K. Rubber-Modified Thermoset Resins; Advances in Chemistry 208; American Chemical Society: Washington, DC, 1984.
    • (1984) Rubber-Modified Thermoset Resins
    • Riew, C.K.1    Gillham, J.K.2
  • 8
    • 3342951726 scopus 로고
    • Advances in Chemistry 222
    • American Chemical Society: Washington, DC
    • Riew, C. K. Rubber Toughened Plastics; Advances in Chemistry 222; American Chemical Society: Washington, DC, 1989.
    • (1989) Rubber Toughened Plastics
    • Riew, C.K.1
  • 9
    • 0003803780 scopus 로고
    • Advances in Chemistry 233
    • American Chemical Society: Washington, DC
    • Riew, C. K.; Kinloch, A. J. Toughened Plastics; Advances in Chemistry 233: American Chemical Society: Washington, DC, 1993, 233.
    • (1993) Toughened Plastics , pp. 233
    • Riew, C.K.1    Kinloch, A.J.2
  • 12
    • 85033817388 scopus 로고
    • Thesis No. 1391, Swiss Federal Institute of Technology
    • Fan Lu, A. Thesis No. 1391, 1995; Swiss Federal Institute of Technology.
    • (1995)
    • Fan Lu, A.1
  • 24
    • 85033811583 scopus 로고    scopus 로고
    • note
    • A general procedure for the preparation and curing is given by the following example utilizing cyclohexane: 1.75 g of epoxy and 0.62 g of diamine were mixed under stirring with a magnetic stirbar in a 20 mL flask together with 0.764 ml of cyclohexane. About 1.5 g of this clear solution was then transferred to a 5 mm diameter glass tube sealed on one end and placed in liquid nitrogen. After sealing the glass tube ander an applied vacuum, the sample was homogenized by melting the cyclohexane at room temperature. This resulted in a foam, which subsequently collapsed, forming a homogeneous, transparent solution. The sealed glass tube was then placed in a preheated sandbath at 80 °C for 20 h. The sample tube was then opened and the white solid epoxy-cyclohexane sample was heated to 200°C in a vacuum oven to complete the curing and was held for 120 h to fully evaporate the cyclohexane solvent.


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