Assignment of 13C nuclear magnetic resonance signals in fatty compounds with allylic hydroxy groups

JAOCS, Journal of the American Oil Chemists' Society

Volumn 73, Issue 5, 1996, Pages 661-663

  Knothe, G ^a   Bagby, M O ^a  

^a NATIONAL CENTER FOR AGRICULTURAL UTILIZATION RESEARCH   (United States)

Author keywords

2(E) ene 1,4 diols; Allylic hydroxy groups; Carbon nuclear magnetic resonance; Methylene envelope; Symmetrical compounds

Indexed keywords

ALCOHOLS; CARBON; FATTY ACIDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OLEFINS; SYNTHESIS (CHEMICAL);

ALKENOLS; ALLYLIC HYDROXY GROUPS; FATTY COMPOUNDS;

OILS AND FATS;

EID: 0030142033     PISSN: 0003021X     EISSN: None     Source Type: Journal    
DOI: 10.1007/BF02518124     Document Type: Article

References (9)

1. 13C NMR Spectroscopy of Lipids, in Advances in Lipid Methodology - Two, edited by W.W. Christie, The Oily Press, Dundee, 1993, pp. 1-68.
2. 13C NMR Nuclear Magnetic Resonance Studies of Olefinic Fatty Acids and Esters, Chem. Phys. Lipids 18:115-129 (1977).
3. Knothe, G., D. Weisleder, M.O. Bagby, and R.E. Peterson, Hydroxy Fatty Acids Through Hydroxylation of Oleic Acid with Selenium Dioxide/tert.-Butylhydroperoxide, J. Am. Oil Chem. Soc. 70:401-404 (1993).
4. Knothe, G., M.O. Bagby, D. Weisleder, and R.E. Peterson, Allylic Mono- and Dihydroxylation of Isolated Double Bonds with Selenium Dioxide-tert.-Butylhydroperoxide. NMR Characterization of Long-Chain Enols, Allylic and Saturated 1,4-Diols, and Enones, J. Chem. Soc., Perkin Trans. 2:1661-1669 (1994) (the supplement to this publication may be ordered from the J. Chem. Soc., Perkin Trans.).
5. Knothe, G., M.O. Bagby, D. Weisleder, and R.E. Peterson, Allylic Mono- and Dihydroxylation of Isolated Double Bonds with Selenium Dioxide-tert.-Butylhydroperoxide. NMR Characterization of Long-Chain Enols, Allylic and Saturated 1,4-Diols, and Enones, J. Chem. Soc., Perkin Trans. 2:1661-1669 (1994) (the supplement to this publication may be ordered from the J. Chem. Soc., Perkin Trans.).
6. Knothe, G., M.O. Bagby, D. Weisleder, and R.E. Peterson, Allylic Hydroxy Fatty Compounds with Δ5-, Δ7-, Δ8-, and Δ10-Unsaturation, J. Am. Oil Chem. Soc. 72:703-706 (1995).
7. Knothe, G., M.O. Bagby, and D. Weisleder, Fatty Alcohols Through Hydroxylation of Symmetrical Alkenes with Selenium Dioxide/tert.-Butylhydroperoxide, Ibid. 72:1021-1026 (1995).
8. Parra, J.L., J. Pastor, F. Comelles, M.A. Manresa, and M.P. Bosch, Studies of Biosurfactants Obtained from Olive Oil, Tenside Surfactants, Deterg. 27:302-306 (1990).
9. Knothe, G., M.O. Bagby, R.E. Peterson, and C.T. Hou, 7,10-Dihydroxy-8(E)-Octadecenoic Acid: Stereochemistry and a Novel Derivative, 7,10-Dihydroxyoctadecanoic Acid, J. Am. Oil Chem. Soc. 69:367-371 (1992).