Chemical mass transfer modelling of ore-forming hydrothermal systems: Current practise and problems

Ore Geology Reviews

Volumn 10, Issue 3-6 SPEC. ISS., 1996, Pages 319-338

  Heinrich, C A ^a   Walshe, J L ^b   Harrold, B P ^c  

^a ETH ZURICH   (Switzerland)

^b Australian National University ^*  (Australia)

^c AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

Author keywords

[No Author keywords available]

Indexed keywords

CHANNEL FLOW; COMPUTER SIMULATION; FLUID STRUCTURE INTERACTION; MASS TRANSFER; MATHEMATICAL MODELS; ORE DEPOSITS; ORES; REDOX REACTIONS; ROCKS; SILICATES; SOLID SOLUTIONS; THERMODYNAMICS;

CHEMICAL MASS TRANSFER; FLUID ROCK INTERACTION; HYDROTHERMAL SYSTEMS;

EXPLORATORY GEOCHEMISTRY;

FLUID/ROCK INTERACTION; HYDROTHERMAL SYSTEM; MASS TRANSFER MODELLING; MINERALIZATION; ORE FORMATION; THERMODYNAMICS;

EID: 0030135625     PISSN: 01691368     EISSN: None     Source Type: Journal    
DOI: 10.1016/0169-1368(95)00029-1     Document Type: Article

References (78)

1. Ague, J.J. and Brimhall, G.H., 1989. Geochemical modelling of steady state fluid flow and chemical reaction during supergene enrichment of porphyry copper deposits. Econ. Geol., 84: 506-528.
2. Barnes, H.L., 1979. Geochemistry of Hydrothermal Ore Deposits. New York, Wiley, 798 pp.
3. Barsukov, V.L., Baranov, E.N., Volosov, A.G. and Grinenko, V.A., 1991. Means of developing and improving the principles of the geochemical methods of predicting concealed mineralization. Geochem. Int., 28: 1-10.
4. Baumgartner, L.P. and Rumble, D., III., 1988. Transport of stable isotopes 1: Development of a kinetic continuum theory for stable isotope transport. Contrib. Mineral. Petrol., 98: 417-430.
5. Benning, L.G. and Seward, T.M., 1995. Hydrosulphide complexing of gold(I) in hydrothermal solutions from 150 to 500°C and 500 to 1500 bars. Geochim. Cosmochim. Acta, submitted.
6. 2. J. Petrol., 29: 445-522.
7. Bickle, M. and Baker, J., 1990. Migration of reaction and isotopic fronts in infiltration zones: assessments of fluid flux in metamorphic terrains. Earth Planet. Sci. Lett., 98: 1-13.
8. Blattner, P. and Lassey, K.R., 1989. Stable-isotope exchange fronts, Damköhler numbers and fluid to rock ratios. Chem. Geol., 78: 381-392.
9. Bowers, T.S., 1991. The deposition of gold and other metals: Pressure-induced fluid immiscibility and associated stable isotope signatures. Geochim. Cosmochim. Acta, 55: 2417-2434.
10. Bowers, T. and Taylor, H.P., Jr., 1987. Some calculations pertaining to an integrated chemical and stable-isotope model of the origin of mid-ocean ridge hydrothermal systems. In: H.C. Helgeson (Editor), Chemical Transport in Metasomatic Processes. Reidel, Dordrecht, pp. 633-655.
11. Candela, P.A., 1989. Magmatic ore-forming fluids: Thermodynamic and mass transfer calculations of metal concentrations. In: J.A. Whitney and A.J. Naldrett (Editors), Ore Deposition associated with Magmas. Rev. Econ. Geol., 4: 203-221.
12. Cartwright, I., 1994. The two-dimensional pattern of metamorphic fluid flow at Mary Kathleen, Australia: Fluid focusing, transverse dispersion and implications for modeling fluid flow. Am. Mineral., 79: 526-535.
13. Caruso, L.J., Bird, D.K., Cho, M. and Liou, J.G., 1988. Epidotebearing veins in the State 2-14 drill hole: Implications for hydrothermal fluid composition. J. Geophys. Res., 93: 13123-13133.
14. Cathles, L.M., 1977. An analysis of cooling of intrusives by ground-water convection which includes boiling. Econ. Geol., 72: 804-826.
15. Cathles, L.M., 1991. The importance of vein selvaging in controlling the intensity and character of subsurface alteration in hydrothermal systems. Econ. Geol., 86: 466-471.
16. Cho, M., Liou, J.G. and Bird, D.K., 1988. Prograde phase relations in the State 2-14 well metasandstones, Salton Sea geothermal field. California. J. Geophys. Res., 93: 13081-13103.
17. Cline, J.S., Bodnar, R.J. and Rimstidt, J.D., 1992. Numerical simulation of fluid flow and silica transport and deposition in boiling hydrothermal solutions: Application to epithermal gold deposits. J. Geophys. Res., 97: 9085-9103.
18. Cox, S.F., Wall, V.J., Etheridge, M.A. and Potter, T.F., 1991. Deformational and metamorphic processes in the formation of mesothermal vein-hosted gold deposits-examples from the Lachlan fold belt in central Victoria. Australia. Ore Geol. Rev., 6: 391-423.
19. Dipple, G.M. and Ferry, J.M., 1992. Metasomatism and fluid flow in ductile fault zones. Contrib. Mineral. Petrol., 112: 149-164.
20. Drummond, S.E. and Ohmoto, H., 1985. Chemical evolution and mineral deposition in boiling hydrothermal systems. Econ. Geol., 80: 126-147.
21. Ferry, J.M. and Dipple, G.M., 1991. Fluid flow, mineral reactions and metasomatism. Geology, 19: 211-214.
22. Ferry, J.M. and Dipple, G.M., 1992. Models for coupled fluid flow, mineral reaction and isotopic alteration during contact metamorphism: The Notch Peak aureole, Utah. Am. Mineral., 77: 577-591.
23. Hardie, L.A. and, Eugster, H.P., 1970. The evolution of closed basin brines. Mineral. Soc. Am. Spec. Pap., 3: 273-290.
24. Haynes, D.W. and Bloom, M.S., 1987. Stratiform copper deposits hosted by low-energy sediments: III. Aspects of metal transport. Econ. Geol., 82: 635-648.
25. Haynes, D.W., Cross, K.C., Bills, R.T. and Reed, M.H., 1995. Olympic Dam ore genesis: a fluid mixing model. Econ. Geol., 90: 281-307.
26. Heinrich, C.A., 1990. The chemistry of tin (-tungsten) ore deposition. Econ. Geol., 85: 529-550.
27. Heinrich, C.A. and Eadington, P.J., 1986. Thermodynamic predictions of the hydrothermal chemistry of arsenic and their significance for the paragenetic sequence of some cassiterite-arsenopyrite-base metal sulfide deposits. Econ. Geol., 81: 511-529.
28. Heinrich, C.A. and Ryan, C.G., 1992. Mineral paragenesis and regional zonation of granite-related Sn-As-Cu-Pb-Zn deposits: a chemical model for the Mole Granite district (Australia) based on PIXE fluid inclusion analyses. In: Y.K. Kharaka and A.S. Maest (Editors). Fluid-Rock Interaction. Balkema Rotterdam, pp. 1583-1587.
29. Heinrich, C.A., Andrew, A.S., Wilkins, R.W.T. and Patterson, D.J., 1989. A fluid inclusion and stable isotope study of synmetamorphic copper ore formation at Mount Isa. Australia. Econ. Geol., 84: 529-550.
30. Heinrich, C.A., Bain, J.H.C., Mernagh, T.P., Wyborn, L.A.I., Andrew, A.S. and Waring, C.L., 1995. Fluid and mass transfer during metabasalt alteration and copper mineralization at Mount Isa, Australia. Econ. Geol., 90: 705-730.
31. Helgeson, H.C., 1970. A chemical and thermodynamic model of ore deposition in hydrothermal systems. Mineral. Soc. Am. Spec. Pap., 3: 155-186.
32. Helgeson, H.C., 1979. Mass transfer among minerals and hydrothermal solutions. In: H.L. Barnes (Editor), Geochemistry of Hydrothermal Ore Deposits. Wiley, New York, N.Y., pp. 568-610.
33. Helgeson, H.C., Garrels, R.M. and McKenzie, F.T., 1969. Evaluation of irreversible reactions in geochemical processes involving minerals and aqueous solutions - II. Applications. Geochim. Cosmochim. Acta, 33: 455-481.
34. Helgeson, H.C., Brown, T.H., Nigrini, A. and Jones, T.A., 1970. Calculation of mass transfer in geochemical processes involving aqueous solutions. Geochim. Cosmochim. Acta. 34: 569-592.
35. 2. J. Metamorphic Geol., 8: 89-124.
36. Holyland, P.W., 1987. Dynamic modelling at the Renison tin mine. Pacific Rim Congress '87, Ext. Abstr., pp. 189-193.
37. Johnson, J.W., Oelkers, E.H. and Helgeson, H..C., 1992. SUPCRT92: A software package for calculating the standard molal thermodynamic properties of minerals, gases, aqueous species and reactions from 1 to 5000 bars and 0° to 1000°C. Computers Geosci., 18: 899-947.
38. Korzhinskii, D.S., 1970. The Theory of Metasomatic Zoning. Clarendon Press, Oxford.
39. Lichtner, P.C., 1988. The quasi-stationary state approximation to coupled mass transport and fluid-rock interaction in a porous medium. Geochim. Cosmochim. Acta. 52: 143-165.
40. Matthäi, S., 1994. Geology and fluid/rock interaction at the Cosmopolitan-Howley gold deposit. N.T., Australia. Lnpubl. Ph.D. thesis. Australian National University, Canberra.
41. McKibben, M.A. and Eldridge, C.S., 1989. Sulfur isotopic variations among minerals and aqueous species in the Salton Sea geothermal system: A SHRIMP ion microprobe and conventional study of active ore genesis in a sediment-hosted environment. Am. J. Sci., 289: 661-707.
42. McKibben, M.A. and Williams, A.E., 1989. Metal speciation and solubility in saline hydrothermal fluids: An empirical approach based on geothermal brine data. Econ. Geol., 84: 1996-2007.
43. McKibben, M.A., Williams A.E., Elders W.A. and Eldridge, C.S. 1987. Saline brines and metallogenesis in a modern sediment-filled rift: the Salton Sea geothermal system. California. U.S.A. Appl. Geochem., 2: 563-578.
44. McKibben, M.A., Andes, J.P. and Williams, A.E., 1988. Active ore formation at a brine interface in metamorphosed deltaic lacustrine sediments: the Salton Sea geothermal system. California. Econ. Geol., 83: 511-523.
45. Merino, E., Moore, C., Ortoleva, P. and Ripley, E., 1986. Mineral zoning in sediment-hosted copper-iron sulfide deposits - a quantitative kinetic approach. In: G.H. Friedrich (Editor). Geology and Metallogeny of Copper Deposits. Springer. Heidelberg, pp. 559-571.
46. Mikucki, E.J. and Heinrich, C.A., 1993. Vein- and mine-scale wall-rock alteration and gold mineralisation in the Archaean Mount Charlotte deposit. Kalgoorlie. Western Australia. Austral. Geol. Surv. Org. Rec., 1993/54: 135-140.
47. Neall, F.B. and Phillips, G.N., 1987. Fluid-wall rock interaction in an Archean hydrothermal gold deposit: a thermodynamic model for the Hunt Mine. Kambalda. Econ. Geol., 82: 1679-1694.
48. Nordstrom, D.K. and Munoz, J.L., 1985. Geochemical Thermodynamics. Benjamin/Cummings. Menlo Park, Calif., 477 pp.
49. Oelkers, E.H. and Helgeson, H.C., 1990. Triple-ion anions and polynuclear complexing in supercritical electrolyte solutions. Geochim. Cosmochim. Acta. 54: 727-738.
50. Oelkers, E.H. and Helgeson, H.C., 1991. Calculation of activity coefficients and degrees of formation of neutral ion pairs in supercritical electrolyte solutions. Geochim. Cosmochim. Acta, 55: 1235-1251.
51. Plummer, L.N., Parkhurst, D.L. and Thorstenson, D.C. 1983. Development of reaction models for ground-water systems. Geochim. Cosmochim. Acta, 47: 665-686.
52. Phillips, O.M., 1991. Flow and Reactions in Permeable Rocks. Cambridge University Press. Cambridge. 277 pp.
53. 2O-NaCl. Am. J. Sci., in press.
54. Reed, M.H., 1982. Calculation of multicomponent chemical equilibria and reaction progress in systems involving minerals, gases and an aqueous phase. Geochim. Cosmochim. Acta, 46: 513-528.
55. Reed, M.H., 1983. Seawater-basalt interaction and the origin of greenstones and related ore deposits. Econ. Geol., 78: 466-485.
56. Reed, M. and Spycher, N., 1984. Calculation of pH and mineral equilibria in hydrothermal waters with application to geothermometry and studies of boiling and dilution. Geochim. Cosmochim. Acta, 48: 1479-1492.
57. Ridley, J.R., Heinrich, C.A. and Mikucki, E.J., 1991. Chemical implications of imperfectly channellized fluid flow in hydrothermal systems. I. Fundamental aspects. II. Application to gold deposits. Aust. Bur. Miner. Resour. Geol. Geophys. Rec., 1990/95: 31-32; 70.
58. Ridley, J.R., Mikucki, E.J. and Groves, D.I., 1995. Archaean lode-gold deposits: fluid flow and chemical evolution in vertically extensive hydrothermal systems. Ore Geol. Rev., this issue.
59. Rose, A.W. and and Burt, D.M., 1979. Hydrothermal alteration. In: H.L. Barnes (Editor). Geochemistry of Hydrothermal Ore Deposits. Wiley. New York, N.Y., pp. 173-235.
60. Ryan, C.G., Heinrich, C.A., Van Achterberg, E., Ballhaus, C. and Mernagh, T.P., 1995. Microanalysis of ore-forming fluids using the Scanning Proton Microprobe. Nuclear Instrum. Methods. Sect. B. in press.
61. Sass, J.H., Priest, S.S., Duda, L.E., Carson, C.C., Hendricks, J.D. and Robison, L.C., 1988. Thermal regime of the State 2-14 well. Salton Sea scientific drilling project. J. Geophys. Res., 93: 12995-13004.
62. Seward, T.M., 1976. The stability of chloride complexes of silver in hydrothermal solutions up to 350°C. Geochim. Cosmochim. Acta. 40: 1329-1341.
63. Seward, T.M., 1989. The hydrothermal chemistry of gold and its implications for ore formation: Boiling and conductive cooling as examples. Econ. Geol. Monogr., 6: 398-404.
64. Sibson, R.H., 1987. Earthquake rupturing as a hydrothermal mineralizing agent. Geology. 15: 701-704.
65. Solomon, M.S. and Groves, D.I., 1994. The geological setting and nature of Australia's mineral deposits. Oxford University Press. Oxford.
66. Spycher, N.F. and Reed, M.H., 1989. Evolution of a Broadlands-type epithermal ore fluid along alternative P-T-paths: Implication for the transport and deposition of base, precious and volatile metals. Econ. Geol., 84: 328-359.
67. Steefel, C.I. and Lasaga, A.C., 1992. Putting transport into water-rock interaction models. Geology, 20: 680-684.
68. Steefel, C.I. and Lasaga, A.C., 1994. A coupled model for transport of multiple chemical species and kinetic precipitation/dissolution reactions with application to reactive flow in single phase hydrothermal systems. Am. J. Sci., 294: 529-592.
69. Sverjensky, D.A., 1987. The role of migrating oil field brines in the formation of sediment-hosted Cu-rich deposits. Econ. Geol., 82: 1130-1141.
70. Sverjensky, D.A., Hemley, J.J. and d'Angelo, W.M., 1991. Thermodynamic assessment of hydrothermal alkali feldsparmica-aluminosilicate equilibria. Geochim. Cosmochim. Acta, 55: 989-1004.
71. Symonds, R.B., Rose, W.I., Reed, M.H., Lichte, F.E. and Finnegan, D. L., 1987. Volatilization, transport and sublimation of metallic and non-metallic elements in high-temperature gases at Merapi Volcano, Indonesia. Geochim. Cosmochim. Acta, 51: 2083-2101.
72. Turnbull, A.C. and Wadsley, M.W., 1986. The CSIRO-SGTE THERMODATA System (Version V). Commonw. Sci. Ind. Res. Org., Port Melbourne, Div. Min. Chem. Commun., 1-7: 413 pp.
73. Uhler, A.D. and Helz, G.R., 1984. Solubility product of galena at 298°K: A possible explanation for apparent supersaturation in nature. Geochim. Cosmochim. Acta, 48: 1155-1160.
74. Van Zeggeren, F., Storey, S.H., 1970. The Computation of Chemical Equilibria. Cambridge University Press, Cambridge.
75. Var'yash, L.N., 1992, Cu(I) complexing in NaCl solutions at 300 and 350°C. Geochem. Int., 29(3): 84-92.
76. Walsh, M.P., Bryant, S.L., Schechter, R.S. and Lake, L.W., 1984. Precipitation and dissolution of solids attending flow through porous media. Am. Inst. Chem. Eng. J., 30: 317-328.
77. Wolery. T.J., 1979. Calculation of chemical equilibrium between aqueous solution and minerals: the EQ3/6 software package. Lawrence Livermore Laboratory URCL-52658, 41 pp.
78. Woodall, R., 1994. Empiricism and concept in successful mineral exploration. Aust. J. Earth Sci., 41: 1-10.