Kinetics of hydrogenation of p-isobutyl acetophenone using a supported Ni catalyst in a slurry reactor

Chemical Engineering Science

Volumn 51, Issue 10, 1996, Pages 1663-1672

  Rajashekharam, M V ^a   Chaudhari, R V ^a  

^a NATIONAL CHEMICAL LABORATORY   (India)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSTS; CATALYTIC; HYDROGENATION; NICKEL; REACTORS; SLURRY;

CATALYST SUPPORTS; CATALYSTS; CHEMICAL REACTORS; DIFFUSION; HYDROGEN; HYDROGENATION; NICKEL; ORGANIC COMPOUNDS; PARTICLE SIZE ANALYSIS; PRESSURE EFFECTS; SLURRIES; ZEOLITES;

BATCH REACTOR MODEL; BATCH SLURRY REACTOR; ISOBUTYL ACETOPHENONE;

REACTION KINETICS;

EID: 0030131275     PISSN: 00092509     EISSN: None     Source Type: Journal    
DOI: 10.1016/0009-2509(96)00025-5     Document Type: Article

References (19)

1. Chaudhari, R.V., Jaganathan, R., Kolhe, D.S., Emig, G., and Hofman, H., 1986, "Kinetic modelling of a complex consecutive reactor in a slurry reactor : Hydrogenation of phenyl acetylene", Chem. Eng. Sci., 41 (12), 141.
2. Chaudhari, R. V., Golap, R.V., Emig, G., Hofmann, H., 1987, "Gas-liquid mass transfer in dead end autoclave", Can. J. Chem. Eng., 65, 774.
3. Daza, L., Pawelec, B., Anderson, J.A., and Fierro, J.L.G., 1992, "Relationship between reduced nickel and activity for benzene hydrogenation on Ni-USY zeolite catalysts", Appl. Catal. A : General, 87, 145.
4. Elango Varadaraj, 1990, "Method for producing Ibuprofen", Hoechst Celanese Corporation, Eur. Pat. 400,892 (Cl.C07c57/30).
5. Froment, G.F., and Bischoff, K.B., 1979. "Chemical reactor analysis and design", Wiley : NY.
6. Joly Vulliemin, C., Gavroy, D., Cordier, G., De Belloefon, C., and Delmas, H., 1994, "Three phase hydrogenation of adiponitrile catalysed by Raney Ni : Kinetic model discrimination and parameter optimization", Chem. Eng. Sci., 49, 4839.
7. Keane, M. A., 1994, "The role of catalyst activation in the enantioselective hydrogenation of methyl acetoacetate over a silicasupported nickel catalysts", Can. J. Chem., 72, 372.
8. Kim, I, 1993, Chemical Engineering, 94
9. Mills, P.L., Ramachandran, P.A., and Chaudhari, R.V., 1992, "Multiphase reaction engineering for fine chemicals and pharmaceuticals", Chem. Eng. Revs., 8, No. 1-2, 1.
10. Molga, E.J., and Westerterp, K.R., 1992, "Kinetics of hydrogenation of 2,4 dinitrotoluene using a 5% Pd on alumina catalyst", Chem. Eng. Sci., 47(7), 1733.
11. Radhakrishnan, K., Ramachandran, P.A., Brahme, P.H., and Chaudhari, R. V., 1983, "Solubility of Hydrogen in Methanol, Nitrobenzene, and their mixtures. Experimental data and correlation", J.Chem. Eng. Data., 28, 1.
12. Ramachandran, P.A., and Chaudhari, R.V., 1983, "Three Phase Catalytic Reactors", Gordon and Breach Science Publishers, NY.
13. Roberts, J.P., 1976, "Hydrogenation Catalysts", Noyes Data Corporation, Park Ridge, NJ, USA.
14. Ryan, D. A., Hoechst Celanese Corporation., 1990, Eur: Pat. EP 358,-120 (CI.C07C33/20)
15. Saeki, K., and Shimakoyi, Daicel Chemical Co. Ltd., 1990, Japan Kokai Tokkyo Koho, JP 0262847 (Cl.C07C33/20)
16. Sano, Y., Yamaguchi, N., Adachi, T., 1974 "Mass transfer coefficients for suspended particles in agitated vessels and bubble columns", J. Chem. Eng. Jpn., 1 255.
17. Satterfield, C.N., 1970, "Mass transfer in Heterogeneous Catalysis", MIT Press, Cambridge
18. Shawn D. L., Diane, K.S., Vannice, M.A., 1994, " Influence of metal support effects on acetophenone hydrogenation over platinum", Appl. Catal A : General, 113, 59.
19. Wilke, C.R., and Chang, P., 1955, "Correlations of diffusion coefficients in dilute solutions", AIChE. J., 1, 264