A scanning tunneling microscopy study of the oxidation of CO on Cu(110) at 400 K: Site specificity and reaction kinetics

Surface Science

Volumn 349, Issue 3, 1996, Pages 275-293

  Crew, W W ^a   Madix, R J ^a  

^a Stanford University   (United States)

Author keywords

Carbon monoxide; Catalysis; Chemisorption; Copper; Copper oxides; Low index single crystal surfaces; Molecule solid reactions; Oxidation; Oxygen; Scanning tunneling microscopy; Stepped single crystal surfaces

Indexed keywords

CARBON MONOXIDE; CATALYSIS; CHEMISORPTION; COMPUTER SIMULATION; COPPER; COPPER OXIDES; CRYSTAL DEFECTS; REACTION KINETICS; SCANNING TUNNELING MICROSCOPY; SINGLE CRYSTALS; SURFACE STRUCTURE; SURFACES;

KINK DEFECTS; MOLECULE SOLID REACTIONS; OVERLAYER STRUCTURE; SITE SPECIFICITY;

OXIDATION;

EID: 0030127970     PISSN: 00396028     EISSN: None     Source Type: Journal    
DOI: 10.1016/0039-6028(96)80026-4     Document Type: Article

References (39)

1. L. Ruan, F. Besenbacher, I. Stensgaard and E. Lægsgaard, Phys. Rev. Lett. 69 (1992) 3523.
2. H.-J. Güntherodt and R. Wiesendanger, Scanning Tunneling Microscopy I: General Principles and Applications to Clean and Adsorbate-Covered Surfaces (Springer, New York, 1992).
3. F.M. Leibsle, S.M. Francis, R. Davis, N. Xiang, S. Haq and M. Bowker, Phys. Rev. Lett. 72 (1994) 2569.
4. T.A. Land, T. Michely, R.J. Behm, J.C. Hemminger and G. Comsa, J. Chem. Phys. 97 (1992) 6774.
5. D. Coulman, J. Wintterlin, R.J. Behm and G. Ertl, Phys. Rev. Lett. 64 (1990) 1761.
6. D. Dorenbos, M. Breeman and D.O. Boerma, Phys. Rev. B 47 (1993) 1580.
7. U. Döbler, K. Baberschke, J. Haase and A. Puschmann, Phys. Rev. Lett. 52 (1984) 1437.
8. H. Niehus and G. Comsa, Surf. Sci. 140 (1984) 18.
9. S.R. Parkin, H.C. Zheng, M.Y. Zhou and A.R. Mitchell, Phys. Rev. B 41 (1990) 5432.
10. R. Freidenhans'l, F. Grey, R.L. Johnson, S.G.J. Mochrie, J. Bohr and M. Nielsen, Phys. Rev. B 41 (1990) 5420.
11. J. Wintterlin, R. Schuster, D. Coulman, G. Ertl and R.J. Behm, J. Vac. Sci. Technol. B 9 (1991) 902.
12. K. Kern, H. Niehus, A. Schatz, P. Zeppenfeld, J. Goerge and G. Comsa, Phys. Rev. Lett. 67 (1991) 855.
13. F.H.P.M. Habraken and G.A. Bootsma, Surf. Sci. 87 (1979) 333.
14. F.H.P.M. Habraken, G.A. Bootsma, P. Hofmann, S. Hachicha and A.M. Bradshaw, Surf. Sci. 88 (1979) 285.
15. O.P. van Pruissen, M.M.M. Dings and O.L.J. Gijzeman, Surf. Sci. 179 (1987) 377.
16. M.E. Domagala and T.C. Campbell, Catal. Lett. 9 (1991) 65.
17. W.W. Crew, X.-C. Guo and R.J. Madix, Surf. Sci., to be published.
18. W.W. Crew and R.J. Madix, Rev. Sci. Instrum., 66 (1995) 4552.
19. J. Frohm, J.F. Wolf, K. Besocke and M. Teske, Rev. Sci. Instrum. 60 (1989) 1200.
20. Y. Kuk, F.M. Chua, P.J. Silverman and J.A. Meyer, Phys. Rev. B 41 (1990) 12393.
21. C. Harendt, J. Goshnick and W. Hirschwald, Surf. Sci. 152/153 (1985) 435.
22. T. Schneider and W. Hirschwald, Catal. Lett. 16 (1992) 335.
23. J.S. Ozcomert, W.W. Pai, N.C. Bartelt and J.E. Reutt-Robey, Phys. Rev. Lett. 72 (1994) 258.
24. G. Hoogers and D.A. King, Surf. Sci. 286 (1993) 306.
25. F.M. Leibsle, P.W. Murray, S.M. Francis, G. Thornton and M. Bowker, Nature 363 (1993) 706.
26. F.M. Leiblse, S.M. Francis, S. Haq and M. Bowker, Surf. Sci. 318 (1994) 46.
27. T. Hill, An Introduction to Statistical Thermodynamics (Dover, New York, 1986).
28. C.-L. Liu and J.B. Adams, Surf. Sci. 294 (1993) 211.
29. M. Boudart, Kinetics of Chemical Processes (Prentice Hall, Englewood Cliffs, NJ, 1968).
30. B. Afsin, P.R. Davies, A. Pashusky, M.W. Roberts and D. Vincent, Surf. Sci. 284 (1993) 109.
31. T. Sasaki, T. Sueyoshi and Y. Iwasawa, Surf. Sci. 316 (1994) L1081.
32. M.W. Roberts, Chem. Soc. Rev. 18 (1989) 451.
33. D. Ghaleb and B. Perraillon, Surf. Sci. 162 (1985) 103.
34. M. Poensgen, J.F. Wolf, J. Frohm, M. Giesen and H. Ibach, Surf. Sci. 274 (1992) 430.
35. K.W. Jacobsen and J.K. Nørskov, Phys. Rev. Lett. 65 (1990) 1788.
36. U. Döbler, K. Baberschke, J. Haase and A. Puschmann, Phys. Rev. Lett. 52 (1984) 1437.
37. M. Bader, A. Puschmann, C. Ocal and J. Haase, Phys. Rev. Lett. 57 (1986) 3273.
38. J.F. Wendelken, Surf. Sci. 108 (1981) 605.
39. L. Ruan, I. Stensgaard, E. Lægsgaard and F. Besenbacher, Surf. Sci. 314 (1994) L873.