Evidence for Parallel Pathways in the Facilitated Transport of Alkenes through Ag+-Exchanged Nafion Films

Industrial and Engineering Chemistry Research

Volumn 35, Issue 4, 1996, Pages 1090-1096

  Rabago, Roberto ^c   Bryant, Debra L ^a   Koval, Carl A ^a   Noble, Richard D ^b  

^a UNIVERSITY OF COLORADO   (United States)

^b UCB 450   (United States)

^c NATIONAL RENEWABLE ENERGY LABORATORY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ION EXCHANGE MEMBRANES; MATHEMATICAL MODELS; OLEFINS; SATURATION (MATERIALS COMPOSITION); SILVER; TRANSPORT PROPERTIES;

FACILITATED TRANSMEMBRANE FLUXES; NAFION FILMS; PARALLEL PATHWAYS; SEPARATION FACTOR; SOLUTE CONCENTRATION;

EXTRACTION;

EID: 0030127663     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie9503306     Document Type: Article

References (17)

1. Eisenberg, A.; Yeager, H. L. Perfluorinated Ionomer Membranes; American Chemical Society: Washington, DC, 1982.
2. Gronowski, A. A.; Yeager, H. L. Factors Which Affect the Permselectivity of Nafion Membranes in Chlor-Alkali Electrolysis, I. J. Electrochem. Soc. 1991, 138, 2690.
3. Hinatsu, J. T.; Mizuhata, M.; Takenaka, H. Water Uptake of Perfluorosulfonic Acid Membranes from Liquid Water and Water Vapor. J. Electrochem. Soc. 1994, 141, 1493.
4. Koval, C. A.; Spontarelli, T. Condensed Phase Facilitated Transport of Olefins Through an Ion Exchange Membrane. J. Am. Chem. Soc. 1988, 110, 293.
5. Koval, C. A.; Spontarelli, T.; Noble, R. D. Styrene/Ethylbenzene Separation Using Facilitated Transport through Perfluorosulfonate Ionomer Membranes. Ind. Eng. Chem. Res. 1989, 28, 1020.
6. Koval, C. A.; Spontarelli, T.; Thoen, P. M.; Noble, R. D. Swelling and Thickness Effects on the Separation of Styrene and Ethylbenzene Based on Facilitated Transport through Ionomer Membranes. Ind. Eng. Chem. Res. 1992, 31, 1116.
7. Malinski, T.; Taha, Z. Nitric Oxide Release from a Single Cell Measured In-Situ by a Porphorinic-Based Microsensor. Nature 1992, 358, 676.
8. Murray, R. W.; Ewing, A. G.; Durst, R. A. Chemically Modified Electrodes. Anal. Chem. 1987, 59, 379.
9. Nagy, G.; Gerhardt, G. A.; Oke, A. F.; Rice, M. E.; Adams, R. N.; Moore, R. B.; Szentirmay, M. N.; Martin, C. R. Ion Exchange and Transport of Neurotransmitters in Nafion Films on Conventional Electrodes and Microelectrode Surfaces. J. Electroanal. Chem. 1985, 188, 85.
10. Poltarzewski, Z.; Staiti, P.; Alderucci, V.; Wieczorek, W.; Giordano, N. Nafion Distribution in Gas Diffusion Electrodes for Solid Polymer Electrolyte Fuel Cell Applications. J. Electrochem. Soc. 1992, 139, 761.
11. Rabago, R.; Noble, R. D.; Koval, C. A. Effects of Incorporation of Fluorocarbon and Hydrocarbon Surfactants into Perfluorosulfonic Acid (Nafion) Membranes. Chem. Mater. 1994, 6, 947.
12. Springer, T. E.; Zawodzinski, T. A.; Gottesfeld, S. Polymer Electrolyte Fuel Cell Model. J. Electrochem. Soc. 1991, 138, 2334.
13. +-Incorporated Ion-Exchange Membranes. Doctoral Thesis, University of Colorado, Boulder, CO, 1993.
14. Thoen, P. M.; Noble, R. D.; Koval, C. A. Unexpectedly Large Selectivities for Olefin Separations Utilizing Silver Ion in Ion Exchange Membranes. J. Phys. Chem. 1994, 98, 1262.
15. Way, J. D.; Noble, R. D. Competitive Facilitated Transport of Acid Gases in Perfluorosulfonic Acid Membranes. J. Membr. Sci. 1989, 46, 309.
16. 2 in Ion Exchange Membranes. AIChE J. 1987, 33, 480.
17. Whiteley, L. D.; Martin, C. R. Perfluorosulfonate Ionomer Film Coated Electrodes as Electrochemical Sensors: Fundamental Investigations. Anal. Chem. 1987, 59, 1746.