Recovery of Propylene Glycol from Dilute Aqueous Solutions by Complexation with Organoboronates in Ion-Pair Extractants

Industrial and Engineering Chemistry Research

Volumn 35, Issue 4, 1996, Pages 1206-1214

  Broekhuis, Robert R ^a   Lynn, Scott ^a   King, C Judson ^a  

^a University of California   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AGGLOMERATION; BORON COMPOUNDS; CALCULATIONS; COMPLEXATION; EXTRACTION; IONS; KETONES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PH; SOLUTIONS; TOLUENE; XYLENE;

ACIDIFICATION; ALIQUOT; DIISOBUTYL KETONE; ETHYLHEXANOL; ION PAIR EXTRACTANTS; ORGANOBORATES; PHENYLBORONATE; PROPYLENE GLYCOL; REGENERATION;

GLYCOLS;

AQUEOUS SOLUTIONS; EXTRACTION; PROPYLENE GLYCOL;

EID: 0030111680     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie950508o     Document Type: Article

References (7)

1. Arenson, D. R.; King, C. J. Separation of low molecular weight alcohols from dilute aqueous solutions by reversible chemical complexation. Report LBL-24944; Lawrence Berkeley Laboratory: Berkeley, CA, 1989.
2. Broekhuis, R. R.; Lynn, S.; King, C. J. Recovery of propylene glycol from dilute aqueous solutions via reversible reaction with aldehydes. Ind. Eng. Chem. Res. 1994, 33, 3230.
3. Broekhuis, R. R.; Lynn, S.; King, C. J. Recovery of propylene glycol from dilute aqueous solutions by reversible chemical complexation with organoboronates. Report LBL-36913, Lawrence Berkeley Laboratory: Berkeley, CA, March 1995.
4. Cameron, D. C.; Cooney, C. L. A novel fermentation: The production of R-(-)-1,2-propanediol and acetol by clostridium thermosaccharolyticum. Biotechnology 1986, 4, 651.
5. Randel, L. A.; Chow, T. K.-F.; King, C. J. Ion-pair extraction of multi-OH compounds by complexation with organoboronate. Solvent Extr. Ion Exch. 1994, 12, 765.
6. Senkus, M. Recovery of 2,3-butanediol produced by fermentation. Ind. Eng. Chem. 1946, 38, 913.
7. Shinbo, T.; Nishimura, K.; Yamaguchi, T.; Sugiura, M. Uphill transport of monosaccharides across an organic liquid membrane. J. Chem. Soc., Chem. Commun. 1986, 349.