Kinetics and Modeling of Carbon Dioxide Absorption into Aqueous Solutions of Diethanolamine

Industrial and Engineering Chemistry Research

Volumn 35, Issue 4, 1996, Pages 1107-1114

  Rinker, Edward B ^a   Ashour, Sami S ^a   Sandall, Orville C ^a  

^a University of California   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION; AQUEOUS SOLUTIONS; CARBON DIOXIDE;

AMINES; CARBON DIOXIDE; CHEMICAL EQUIPMENT; DIFFUSION; MASS TRANSFER; MATHEMATICAL MODELS; REACTION KINETICS; SOLUTIONS;

DIETHANOLAMINE; KINETIC RATE COEFFICIENTS; LAMINAR LIQUID JET ABSORBER; PENETRATION THEORY; REVERSIBLE REACTIONS; ZWITTERION MECHANISM;

ABSORPTION;

EID: 0030111661     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie950336v     Document Type: Article

References (34)

1. Al-Ghawas, H. A.; Hagewiesche, D. P.; Ruiz-Ibanez, G.; Sandall, O. C. Physicochemical properties important for carbon dioxide absorption in aqueous methyldiethanolamine. J. Chem. Eng. Data 1989, 34, 385-391.
2. Alper, E. Reaction mechanism and kinetics of aqueous solutions of 2-amino-2-methyl-1-propanol and carbon dioxide. Ind. Eng. Chem. Res. 1990, 29, 1725-1728.
3. Barth, D.; Tondre, C.; Delpuech, J.-J. Stopped-flow investigation of the reaction kinetics of carbon dioxide with some primary and secondary alkanolamines in aqueous solutions. Int. J. Chem. Kinet. 1986, 18, 445-457.
4. 2 and alkanolamines in aqueous solutions. Chem. Eng. Sci. 1984, 39, 207-225.
5. 2 with the sterically hindered amine 2-amino-methylpropanol at 298 K. Chem. Eng. Sci. 1990, 45, 1167-1173.
6. Brenan, K. E.; Campbell, S. L.; Petzold, L. R. Numerical Solution of Initial-Value Problems in Differential-Algebraic Equations; North-Holland, New York, 1989.
7. Caplow, M. Kinetics of carbamate formation and breakdown. J. Am. Chem. Soc. 1968, 90, 6795-6803.
8. Cotton, F. A.; Wilkinson, G. Advanced Inorganic Chemistry; Interscience Publishers: New York, 1966.
9. Crooks, J. E.; Donnellan, J. P. Kinetics and mechanism of the reaction between carbon dioxide and amines in aqueous solution. J. Chem. Soc., Perkin Trans. 2 1989, 331-333.
10. Danckwerts, P. V. Gas-Liquid Reactions; McGraw-Hill: New York, 1970.
11. 2 with ethanolamines. Chem. Eng. Sci. 1979, 34, 443-446.
12. Danckwerts, P. V.; Sharma, M. M. The absorption of carbon dioxide into solutions of alkalis and amines (with some notes on hydrogen sulphide and carbonyl sulphide). Chem. Engr. 1966, Oct, CE244-CE280.
13. Danckwerts, P. V.; McNeil, K. M. The absorption of carbon dioxide into aqueous amine solutions and the effects of catalysis. Trans. Inst. Chem. Eng. 1967, 45, T32-T49.
14. Davis, R. A.; Sandall, O. C. Kinetics of the reaction of carbon dioxide with secondary amines in polyethylene glycol. Chem. Eng. Sci. 1993, 48, 3187-3193.
15. 2 absorption/desorption in mixtures of methyldiethanolamine with monoethanolamine or diethanolamine. Chem. Eng. Sci. 1991, 46, 2829-2845.
16. Higbie, R. The rate of absorption of a pure gas into a still liquid during short periods of exposure. Trans. Am. Inst. Chem. Eng. 1935, 31, 365.
17. Hikita, H.; Asai, S.; Ishikawa, H.; Honda, M. The kinetics of reactions of carbon dioxide with monoethanolmine, diethanolamine and triethanolamine by a rapid mixing method. Chem. Eng. J. 1977, 13, 7-12.
18. Hikita, H.; Ishikawa, H.; Uku, K.; Murakami, T. Diffusivities of mono-, di-, and triethanolamines in aqueous solutions. J. Chem. Eng. Data 1980, 25, 324-325.
19. 2 with primary and secondary amines in aqueous solutions-II. Influence of temperature on zwitterion formation and deprotonation rates. Chem. Eng. Sci. 1992, 47, 2037-2045.
20. Oloffson, G.; Hepler, L. G. Thermodynamics of ionization of water over wide ranges of temperature and pressure. J. Soln. Chem. 1975, 4, 127.
21. Petzold, L. R. A Description of DASSL: A differential/algebraic system solver. In Scientific Computing; Stepleman, R. S., et al., Eds.; North-Holland: Amsterdam, 1983; pp 65-68.
22. Pinsent, B. R. W.; Pearson, L.; Roughton, F. J. W. The kinetics of combination of carbon dioxide with hydroxide ions. Trans. Faraday Soc. 1956, 52, 1512-1520.
23. Read, A. J. The first ionization constant of carbonic acid from 25 to 250 °C and to 2000 bar. J. Soln. Chem. 1975, 4, 53-70.
24. Rinker, E. B.; Sandall, O. C. Solubility of nitrous oxide in aqueous solutions of methyldiethanolamine, diethanolamine and mixtures methyldiethanolamine and diethanolamine. Canadian Chemical Engineering Conference, Calgary, Canada, 1994.
25. Rinker, E. B.; Oelschlager, D. W.; Colussi, A. T.; Henry, K. R.; Sandall, O. C. Viscosity, density and surface tension of binary mixtures of water and methyldiethanolamine, water and diethanolamine and tertiary mixtures of these amines with water over the temperature range 20-100 °C. J. Chem. Eng. Data 1994, 39, 392-395.
26. Sada, E.; Kumazawa, H.; Han, Q.; Matsuyama, H. Chemical kinetics of the reaction of carbon dioxide with ethanolamines in nonaqueous solvents. AIChE J. 1985, 31, 1297-1303.
27. Savage, D. W.; Kim, C. J. Chemical kinetics of carbon dioxide reactions with diethanolamine and diisopropanolamine in aqueous solutions. AIChE J. 1985, 31, 296-301.
28. 2O in water over the temperature range 293-368 K. J. Chem. Eng. Data 1994a, 39, 330-332.
29. 2O in aqueous solutions of methyldiethanolamine and diethanolamine from 293 to 368 K. J. Chem. Eng. Data 1994b, 39, 396-398.
30. 2 and alkanolamines both in aqueous and nonaqueous solutions-I. Primary and secondary amines. Chem. Eng. Sci. 1988a, 43, 573-585.
31. 2 and alkanolamines both in aqueous and nonaqueous solutions-II. Tertiary amines. Chem. Eng. Sci. 1988b, 43, 587-591.
32. 2 and diethanolamine at 298 K. Chem. Eng. Sci. 1989, 44, 1264-1268.
33. Versteeg, G. F.; Kuipers, J. A. M.; van Beckum, F. P. H.; van Swaaij, W. P. M. Mass transfer with complex reversible chemical reactions-II. Parallel reversible chemical reactions. Chem. Eng. Sci. 1990, 45, 183-197.
34. Wayburn, T. L.; Seader, J. D. Homotopy continuation methods for computer-aided process design. Comput. Chem. Eng. 1987, 11, 7-25.