High-temperature electrical properties in the ThO2-rich region of ThO2-RE2O3 systems

Journal of the American Ceramic Society

Volumn 79, Issue 3, 1996, Pages 756-762

  Hufschmidt, Heike ^a   Weyl, Axel ^a   Janke, Dieter ^a,b  

^a MAX PLANCK INSTITUT FÜR EISENFORSCHUNG GMBH   (Germany)

^b TU BERGAKADEMIE FREIBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

ELECTRIC CONDUCTIVITY OF SOLIDS; ELECTRIC PROPERTIES; HIGH TEMPERATURE PROPERTIES; OXIDES; PHASE COMPOSITION; SOLID ELECTROLYTES; STABILITY; THERMAL VARIABLES MEASUREMENT; THERMODYNAMICS; THORIUM COMPOUNDS; ZIRCONIA;

CHARACTERISTIC PARAMETER; CHEMICAL STABILITY; ELECTRONIC CONDUCTION; HIGH TEMPERATURE ELECTRICAL PROPERTIES; PHASE RELATIONS;

SOLID SOLUTIONS;

EID: 0030109387     PISSN: 00027820     EISSN: None     Source Type: Journal    
DOI: 10.1111/j.1151-2916.1996.tb07939.x     Document Type: Article

References (53)

1. W. Pluschkell and D. Janke, Elektrochemische Sauerstoffmessung in der Metallurgie (Electrochemical Oxygen Measurement in Metallurgy). VDEh Düsseldorf, Stahleisen, Düsseldorf, Germany, 1985.
2. Takahashi and A. Kozawa (Eds.). Application of Solid Electrolytes. VCH Publishers, New York, 1980.
3. S. Dimitrov, "Entwicklung neuer Festelektrolyt-Tauchsonden zur unmittelbaren Messung von Aluminium, Mangan und Chrom in Eisen- und Stahlschmelzen"; Dr.-Ing. Dissertation. Technical University of Clausthal, Clausthal, Germany, 1991.
4. D. Janke, "Ionenleiter," Handb. Keram., 39 [8] 1-8 (1987).
5. W. Pluschkell, "EMK-Messungen in Stahlschmelzen bei kleinen Sauerstoff schalten"; pp. 110-15 in 7èmes Journées Internationales de Sidérurgie. Versailles (1978).
6. 2 als Festelektrolyt zur Messung des Sauerstoffpartialdruckes in Gasen, Metall-Melalloxid-Gemischen und Metallschmelzen"; Dr.-Ing. Dissertation. Technical University of Aachen, Aachen, Germany, 1969.
7. W. A. Fischer and D. Janke, Metallurgische Elektrochemie (Metallurgical Electrochemistry). Springer-Verlag und Verlag Stahleisen, Düsseldorf, Germany, 1975.
8. T. H. Etsell and S. N. Flensas, "The Electrical Properties of Solid Electrolytes," Chem Rev., 70, 339-76 (1970).
9. 2 als Elektrolyt für elektrochemische Untersuchungen bei höheren Temperaturen," Z. Elektrochem. Ber. Bunsenges. Phys. Chem., 66, 572-76 (1962).
10. H. Schmalzried, "Ionen- und Elektronenleitung in binären Oxiden und ihre Untersuchung mittels EMK-Messungen," Z. Phys. Chem. (Munich), 38, 87-102 (1963).
11. W. Baukai, R. Knödler, and W. Kühn, "Überblick über die Anwendungsmöglichkeiten von Feststoffelektrolyten," Chem.-Ing.-Tech., 50, 245-49 (1978).
12. 2 + 11 mol% CaO Solid Electrolyte," Trans. Iron Steel Inst. Jpn., 21, 54-55 (1981).
13. T. H. Etsell and S. N. Flengas, "N-type Conductivity in Stabilized Zirconia Solid Electrolytes," J. Electrochem. Soc., 119, 1-7 (1972).
14. 2 als Ionenleiter- Herstellung und Eigenschaften," Keram. Z., 42, 92-97 (1990).
15. P. Vashishta, J. N. Mundy, and G. K. Shenoy (Eds.), Fast Ion Transport in Solids. Wisconsin, 1979.
16. 2 als Festelektrolyt," Goldschmidt Inf., 59, 16-26 (1983).
17. W. Pluschkell, "Sauerstoffkonzentrationszellen mit Elektronenleitung im Festelektrolyten," Arch. Eisenhüitenwes., 46, 11-18 (1975).
18. D. Janke and H. Richter, "Low Oxygen Activities in Steel Melts - Possibilities and Limits of the Solid Electrolyte Measuring Technique," Arch. Eisenhüttenwes., 50, 93-99 (1979).
19. J. W. Patterson, "Conduction Domains for Solid Electrolytes," J. Elecrtrochem. Soc., 118, 1033-39 (1971).
20. T. H. Etsell, "Transport Properties of Thoria and Thoria-Based Solid Solutions," Z. Naturforsch., A27, 1138-49 (1972).
21. 3 Solutions," Z. Phys. Chem. (Munich), 49, 198-221 (1966).
22. 2," Z. Phys. Chem. (Munich), 69, 11-28 (1970).
23. 1.9," Kernforschungszentrum, 291, 4-11 (1975).
24. H. S. Maiti and E. C. Subbarao, "Electrical Conduction in CaO-Doped Thoria Elecrolytes," J. Electrochem. Soc., 123, 1713-18 (1976).
25. 3)-Festelektrolyten bei 1200 bis 1650°C." Arch. Eisenhüttenwes., 45, 477-82 (1975).
26. 3," J. Phys. Chem. Solids, 49, 1027-34 (1988).
27. 2-Lanthanidenoxiden," J. Solid State Chem., 4, 453-65 (1972).
28. Phase Diagrams for Ceramists, Vol. 1-6. American Ceramic Society, Columbus/Westerville, OH, 1964-87.
29. G. Brauer and H. Gradinger, "Über heterotype Mischphasen bei Seltenerdoxyden I," Z. Anorg. Allg. Chem., 276, 14-31 (1954).
30. 3," Z. Anorg. Allg. Chem., 324, 48-59 (1963).
31. 4+) Solid Solutions," J. Am Ceram. Soc., 72, 1415-21 (1989).
32. 3," J. Mater. Sci., 4, 613-24 (1969).
33. S. Dimitrov, S. Ranganathan, A. Weyl, and D. Janke, "New Reference Materials for Electrochemical On-line Sensors to Measure Steel Bath Composition," Steel Res., 64 [1] 63-70 (1993).
34. A. Weyl, "Untersuchungen zur Ionenleitfähigkeit neuer, phasenstabiler Mischoxidelektrolyte bei 1000 bis 1600°C": Dr.-Ing. Dissertation. Technical University of Clausthal, Clausthal, Germany, 1993.
35. I. Barin and O. Knacke, Thermochemical Properties of Inorganic Substances. Verlag Stahleisen, Düsseldorf, Germany, 1973. Supplement, 1977.
36. O. Knacke, O. Kubaschewski, and K. Hesselmann, Thermochemical Properties of Inorganic Substances I, 2nd ed. Springer-Verlag, Berlin, Germany, 1991.
37. J. F. Elliott, M. Gleiser, and V. Ramakrishna, Thermochemistry for Steelmating, Vol. 2, Thermodynamic and Transport Properties, 1963.
38. JANAF Thermochemical Tables, 2nd ed., Natl. Stand. Ref. Data Ser. (U.S., Natl. Bur. Stand.), 37 (1971).
39. O. Kubaschewski, E. L. Evans, and C. B. Alcock, Metallurgical Thermochemistry, 4th ed. Pergamon, London, U.K., 1967.
40. T. Rosenqvist. Principles of Extractive Metallurgy, 2nd ed. McGraw-Hill, New York, 1983.
41. J. F. Elliott, M. Gleiser, and V. Ramakrishna, Thermochemistry for Steelmating, Vol. 2, Thermodynamic and Transport Properties, 1963.
42. K. Suzuki and K. Sanbongi, Tetsu to Hagane, 58, 1579-93 (1972).
43. I. A. Novochatskii and L. M. Lenev, Russ. J. Inorg. Chem. (Engl. Transl.). 11, 1078-81 (1966).
44. 2 = [O] in Eisenschmelzen," Arch. Eisenhüttenwes., 46, 755-82 (1975).
45. 2 Systems," J. Am. Ceram. Soc., 48, 286-89 (1965).
46. B.-S. Chiou, H.-T. Dai, and J.-G. Duh, "Electrical Behaviour of Ceria-Stabilized Zirconia with Rare-Earth Oxide Additives," J. Am. Ceram. Soc., 73, 866-701 (1990).
47. 2-Based Solid Electrolytes"; pp. 555-71 in Advances in Ceramics, Vol. 12, Science and Technology of Zirconia II. Edited by N. Claussen and A. H. Heuer. American Ceramic Society, Columbus, OH, 1981.
48. A. S. Nowick, D. Y. Wang, D. S. Park, and J. Griffith, Fast Ion Transport in Solids; p. 673. Elsevier, Amsterdam, Netherlands, 1979.
49. 3 (Y-TZP)," J. Am. Ceram. Soc., 69, 573-77 (1986).
50. R. J. Stafford, S. J. Rothman, and J. L. Routbort, "Effect of Dopant Size on the Ionic Conductivity of Cubic Stabilized Zirconia," Solid State Ionics, 37, 67-72 (1989).
51. 2 Stabilized with Rare Earths," Solid State Ionics, 36 189-92 (1989).
52. 3 Solid Solutions," J. Am. Ceram. Soc., 74, 2489-94 (1991).
53. E. Geguzin, Physik des Sinterns. VEB Verlag Grundstoffindustrie, Leipzig, Germany, 1973.