Thermal decomposition of alkoxides in an inert organic solvent: Novel method for the synthesis of homogeneous mullite precursor

Journal of the American Ceramic Society

Volumn 79, Issue 3, 1996, Pages 793-795

  Inoue, Masashi ^a,b   Kominami, Hiroshi ^a,c   Inui, Tomoyuki ^a  

^a KYOTO UNIVERSITY   (Japan)

^b AMERICAN CERAMIC SOCIETY   (United States)

^c KINKI UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

AMORPHOUS MATERIALS; CALCINATION; CHEMICAL REACTIONS; CRYSTALLIZATION; DIFFERENTIAL THERMAL ANALYSIS; ORGANIC SOLVENTS; PYROLYSIS; SILICATES; SYNTHESIS (CHEMICAL); TOLUENE; X RAY POWDER DIFFRACTION;

ALKOXIDES; ALUMINOSILICATE; INERT ORGANIC SOLVENT; MICROCRYSTALS; MULLITE; MULLITIZATION;

OXIDES;

EID: 0030107892     PISSN: 00027820     EISSN: None     Source Type: Journal    
DOI: 10.1111/j.1151-2916.1996.tb07947.x     Document Type: Article

References (28)

1. M. Inoue, Y. Kondo, and T. Inui, "An Ethylene Glycol Derivative of Boehmite," Inorg. Chem., 27 [2] 215-21 (1988).
2. M. Inoue, H. Tanino, Y. Kondo, and T. Inui, "Formation of Microcrystalline α-Alumina by Glycothermal Treatment of Gibbsite," J. Am. Ceram. Soc., 72 [2] 352-53 (1989).
3. M. Inoue, H. Otsu, H. Kominami, and T. Inui, "Synthesis of Yttrium Aluminum Garnet by the Glycothermal Method," J. Am. Ceram. Soc., 74 [6] 1452-54 (1991).
4. M. Inoue, H. Kominami, and T. Inui, "Reaction of Aluminium Alkoxides with Various Glycols and the Layer Structure of Their Products," J. Chem. Soc., Dalton Trans., 3331-36 (1991).
5. M. Inoue, H. Kominami, and T. Inui, "Thermal Transformation of X-Alumina Formed by Thermal Decomposition of Aluminum Alkoxide in Organic Media," J. Am. Ceram. Soc., 75 [9] 2597-98 (1992).
6. M. Inoue, H. Kominami, H. Otsu, and T. Inui, "Synthesis of Microcrystalline Titania in Organic Media," Nippon Kagaku Kaishi, [10] 1364 (1991).
7. M. Inoue, H. Kominami, and T. Inui, "Novel Synthetic Method for the Catalytic Use of Thermally Stable Zirconia: Thermal Decomposition of Zirconium Alkoxides in Organic Media," Appl. Carol. A. 97, L25-L30 (1993).
8. Y. Hirata, K. Sakeda, Y. Matsushila, K. Shimada, and Y. Ishihara, "Characterization and Sintering Behavior of Alkoxide-Derived Aluminosilicate Powders," J. Am. Ceram. Soc., 72 [6] 995-1002 (1989).
9. H. H. W. Moenke, "Silica, the Three-Dimensional Silicates, Borosilicates and Beryllium Silicates"; pp. 365-70 in Mineralogical Society Monograph 4, Infrared Spectra of Minerals. Edited by V. C. Farmer. The Mineralogical Society, London, U.K., 1974.
10. J. Ossaka, "Tetragonal Mullite-like Phase from Coprecipilated Gels," Nature (London), 191 [Sept. 2] 1000-1001 (1961).
11. H. Schneider and T. Rymon-Lipinski, "Occurrence of Pseudotetragonal Mullite," J. Am. Ceram. Soc., 71 [3] C-162-C-164 (1988).
12. T. Ban and K. Okada, "Structure Refinement of Mullite by the Reitveld Method and a New Method for Estimation of Chemical Composition," J. Am. Ceram. Soc., 75 [1] 227-30 (1992).
13. G. W. Brindley and M. Nakahara, "The Kaolinilc-Mullite Reaction Series I-III," J. Am. Ceram. Soc., 42 [7] 311-24 (1959).
14. 3 Xeroeels and the Formation Process of Mullite," J. Am. Ceram. Soc., 69 [9] 652-56 (1986).
15. M. D. Sacks, H.-W. Lee, and J. A. Pask, "A Review of Powder Preparation Methods and Densification Procedures for Fabricating High-Density Mullite"; pp. 167-207 in Ceramics Transactions, Vol. 6, Mullite and Mullite Matrix Composites. Edited by S. Somiya, R. F. Davis, and J. A. Pask. American Ceramic Society, Westerville, OH, 1990.
16. K. Okada, N. Otsuka, and S. Somiya, "Review of Mullite Synthesis Routes in Japan," Am. Ceram. Soc: Bull., 70 [10] 1633-40 (1991).
17. I. A. Aksay, D. M. Dabbs, and M. Sarikaya, "Mullite for Structural, Electronic and Optical Applications," J. Am. Ceram. Soc., 74 [10] 2343-58 (1991).
18. S. Kanzaki, H. Tabata, T. Kumazawa, and S. Ohta, "Sintering and Mechanical Properties of Stoichiometric Mullite," J. An. Ceram. Soc., 68 [1] C-6-C-7 (1985).
19. I. Jaymes and A. Douy, "Homogeneous Mullite-Forming Powders from Spray-Drying Aqueous Solutions," J. Am. Ceram. Soc., 75 [11] 3154-56 (1992).
20. 2 System," J. Am. Ceram Soc., 70 [10] 704-707 (1987).
21. K. Okada and N. Otsuka, "Formation Process of Mullite"; pp. 375-87 in Ceramics Transaction, Vol. 6. Mullite and Mullite Matrix Composites. Edited by S. Somiya, R. F. Davis, and J. A. Pask. American Ceramic Society, Westerville, OH, 1990.
22. 2," J. Am. Ceram. Soc., 67 [7] 468-71 (1984).
23. D. X. Li and W. J. Thomson, "Effects of Hydrolysis on the Kinetics of High-Temperature Transformations in Aluminosilicate Gels," J. Am. Ceram. Soc., 74 [3] 374-78 (1991).
24. 2 Powders Formed by Chemical Vapor Deposition"; pp. 311-22 in Ceramics Transactions, Vol. 6. Mullite and Mullite Matrix Companies. Edited by S. Somiya, R. F. Davis, and J. A. Pask. American Ceramic Society, Westerville," OH, 1990.
25. M. A. Pask and A. P. Tomsia, "Formation of Mullite from Sol-Gel Mixtures and Kaolinite," J. Am. Ceram. Soc., 74 [10] 2367-73 (1991).
26. 3, Powders Prepared from Metal Alkoxide," Yogyo Kyntaishi, 93 [1] 36-44 (1985).
27. H. Suzuki, Y. Tomokiyo, Y. Suyama, and H. Saito, "Processing of the Fine Mullite Powder from Metal-Alkoxides and Its Sintering," Yogyo Kyokaishi, 96 [7] 697-702 (1987).
28. J. C. Huling and G. L. Messing, "Epitactic Nucleation of Spinel in Alumino-silicate Gels and fts Effect on Mullite Crystallization," J. Am. Ceram. Soc., 74 [10] 2374-81 (1991).