Transfer kinetics of metals from molten fission product chloride to liquid lead cathode during electrolysis in pyrometallurgical treatment of highly radioactive waste

Journal of Nuclear Science and Technology

Volumn 33, Issue 3, 1996, Pages 245-249

  Nabeshima, Masahiro ^a   Shimizu, Takafumi ^a   Sakamura, Yoshiharu ^b   Sakata, Masahiro ^b   Inoue, Tadashi ^b  

^a SUMITOMO METAL MINING CO LTD   (Japan)

^b CENTRAL RESEARCH INSTITUTE OF ELECTRIC POWER INDUSTRY   (Japan)

Author keywords

Highly radioactive liquid waste; Interphase mass transfer; Ionic valence; Molten chloride electrolysis; Nuclear fuel reprocessing; Overall mass transfer coefficient; Purex process; Pyrometallurgical waste tratment; Reductive transfer kinetics; Spent fuels

Indexed keywords

CHLORINE COMPOUNDS; ELECTROLYSIS; FISSION PRODUCTS; MASS TRANSFER; METALS; PYROMETALLURGY; REACTION KINETICS;

RADIOACTIVE WASTE PROCESSING;

RADIOACTIVE WASTE DISPOSAL;

EID: 0030092434     PISSN: 00223131     EISSN: None     Source Type: Journal    
DOI: 10.1080/18811248.1996.9731896     Document Type: Article

References (16)

1. Inoue, T., et al. Nucl. Technol., 69, 206 (1991).
2. Inoue, T., et al.: CRIEPIRep. T15, (1990), [in Japanese].
3. Sakata, M.: J. Nucl. Mater., 185, 56 (1991).
4. Kurata, M., et al.: Proc. Int. Conf. on Evaluation ofEmerg. Nucl. Fuel Cycle Systems, Versailles, Vol. l, 1067 (1995).
5. Olander, D.R., Pasternak, A. D.: Proc, on Reprocessing of Nucl. Fuels Nucl. Metallurgy, Vol.15, 467 (1969).
6. Xie, G., Ema, K., Ito, Y.: J. Appl. Electrochem., 24, 321 (1994).
7. Ito, Y.: Yoyuen (Molten salt), 34[1], 64 (1991), [in Japanese].
8. Inoue, T., et al.: Proc. WM’94, Tucson, Arizona, Vol. l, 775 (1994).
9. Fujita, S., Tohata, H.: “Kagaku Kogaku III”, (Chemical Engineering III), Kagaku-dojin, Tokyo, 261 (1972), [in Japanese].
10. Pratt, H.R.C.: “Handbook of Solvent Extractiori’, (ed. by Lo, T.C., Baird, M.H.I., Hanson, C.), John Willey & Sons, 102 (1983).
11. Laddha, G.S., Degaleesan, T.E.: “Transport Phenomena in Liquid Extraction”, Tata McGraw-Hill Pub., 58 (1976).
12. Kusakabe, T., et al.: CRIEPI Rep. T89018, 10 (1989), [in Japanese].
13. Mashiko, N.: “Handbook of Electrochemistry', (ed. by Electrochem. Soc.), Maruzen, 328 (1985), [in Japanese].
14. Sato, Y.: “Fundamentals of Molten Salt and Thermal Technology”, (ed. by Soc. Molten-Salt Thermal Tech.), Agne, 45 (1993), [in Japanese].
15. Asprey, L.B., Penneman, R.A.: Chem. Eng. News, 45, 75 (1967).
16. Johnson, K.E., Mackenzie, J.R.: J. Electrochem. Soc., 116[12], 1697 (1969).