Kinetic and thermodynamic appraisal of a remarkable cyclic mechanism for poly(vinyl chloride) dehydrochlorination

American Chemical Society, Polymer Preprints, Division of Polymer Chemistry

Volumn 37, Issue 1, 1996, Pages 697-698

  Starnes Jr , W H ^a  

^a The College of William and Mary   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHLORINATION; DEHYDROGENATION; GIBBS FREE ENERGY; REACTION KINETICS; THERMODYNAMIC STABILITY;

DEHYDROCHLORINATION;

POLYVINYL CHLORIDES;

EID: 0030091735     PISSN: 00323934     EISSN: None     Source Type: Conference Proceeding    
DOI: None     Document Type: Article

References (20)

1. Iván, B.; Kelen, T.; Tüdos, F. In Degradation and Stabiliza-tion of Polymers; Jellinek, H. H. G.; Kachi, H., Eds.; Elsevier: New York, 1989; Vol. 2, Chapter 8, and references cited therein.
2. Starnes, W. H., Jr.; Girois, S. Polymer Yearbook 1995, 12, 105, and references cited therein.
3. Amer, A. R.; Shapiro, J. S. J. Macromol. Sci., Chem. 1980, 14, 185.
4. Bacaloglu, R.; Fisch, M. Polym. Degrad. Stab. 1994, 45, 301.
5. Bacaloglu, R.; Fisch, M. Polym. Degrad. Stab. 1994, 45, 315.
6. Bacaloglu, R.; Fisch, M. Polym. Degrad. Stab. 1994, 45, 325.
7. Bacaloglu, R.; Fisch, M. Polym. Degrad. Stab. 1995, 47, 9.
8. Bacaloglu, R.; Fisch, M. Polym. Degrad. Stab. 1995, 47, 33.
9. Doering, W. von E.; Sarma, K. J. Am. Chem. Soc. 1992, 114, 6037, and references cited therein.
10. Stull, D. R.; Westrum, E. F., Jr.; Sinke, G. C. The Chemical Thermodynamics of Organic Compounds; Wiley: New York, 1969; p 319.
11. Reference 10; pp 244, 313, 518, and 531.
12. Robinson, P. J.; Skelhorne, G. G.; Waller, M. J. J. Chem. Soc., Perkin Trans. 2 1978, 349.
13. Chytrý, V.; Obereigner, B.; Lím, D. Eur. Polym. J., Suppl. 1969, 379.
14. Chytrý, V.; Obereigner, B.; Lím, D. Eur. Polym. J. 1971, 7, 1111.
15. Boughdady, N. M.; Chynoweth, K. R.; Hewitt, D. G. Aust. J. Chem. 1991, 44, 567.
16. Mayer, Z.; Obereigner, B.; Lím, D. J. Polym. Sci., Part C, Polym. Symp. 1971, 33, 289.
17. Moore, J. W.; Pearson, R. G. Kinetics and Mechanism, 3rd ed.; Wiley: New York, 1981; p 256.
18. Seshadri, S. R.; Starnes, W. H., Jr., unpublished observations.
19. Haddon, R. C.; Starnes, W. H., Jr. Adv. Chem. Ser. 1978, 169, 333.
20. Starnes, W. H., Jr., in preparation for submission to Polymer Degradation and Stability.