Spectroscopic investigation of a series of sodium lanthanide decatungstates, Na7H2Ln(III)(W5O18) 2·nH2O (Ln: La-Yb): The contribution of 4fn electrons to bonding interaction among Ln(III) and polyoxotungstates

Journal of Alloys and Compounds

Volumn 234, Issue 2, 1996, Pages 193-198

  Shiozaki, R ^a   Inagaki, A ^a   Nishino, A ^a   Nishio, E ^b   Maekawa, M ^a   Kominami, H ^a   Kera, Y ^a  

^a KINKI UNIVERSITY   (Japan)

^b Nicolet Japan Co   (Japan)

Author keywords

4fn electrons; 183W NMR; Bonding interaction; FT Raman; Lanthanide decatungstate

Indexed keywords

CHEMICAL BONDS; ELECTRONS; LANTHANUM ALLOYS; MAGNETIC MOMENTS; NUCLEAR MAGNETIC RESONANCE; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RAMAN SPECTROSCOPY; SYNTHESIS (CHEMICAL); TUNGSTEN COMPOUNDS;

FOURIER TRANSFORM RAMAN STRETCHING FREQUENCIES; POLYOXOTUNGSTATES; SODIUM LANTHANIDE DECATUNGSTATES;

SODIUM COMPOUNDS;

EID: 0030082960     PISSN: 09258388     EISSN: None     Source Type: Journal    
DOI: 10.1016/0925-8388(95)02112-4     Document Type: Article

References (22)

1. J.A. Peters, J. Magn. Reson., 68 (1986) 240, and references cited therein.
2. R.J.A. Abraham, H.A. Bergen, D.J. Chadwick and F. Sancassan, J. Chem. Soc. Chem. Commun., (1982) 998.
3. (a) L.E. Orgel, Disc. Faraday Soc., 26 (1958) 93;
4. (b) R.G. Shulman and B.J. Wyluda, J. Chem. Phys., 30 (1959) 335.
5. W.B. Lewis, J.A. Jackson, J.F. Lemons and H. Taube, J. Chem. Phys., 36 (1962) 694.
6. R.M. Golding and M.P. Halton, Aust. J. Chem., 25 (1972) 2577; R.M. Golding and P.Pyykko, Mol. Phys., 26 (1973) 1389.
7. R.M. Golding and M.P. Halton, Aust. J. Chem., 25 (1972) 2577; R.M. Golding and P.Pyykko, Mol. Phys., 26 (1973) 1389.
8. M.A. Fedotov, B.Z. Pertsikov and D.K. Danovich, Polyhedron, 9 (1990) 1249.
9. R. Shiozaki, H. Gotoh and Y. Kera, Bull. Chem. Soc. Jpn., 66 (1993) 2790; R. Shiozaki, H. Kominami and Y. Kera, Synth. Commun., in press.
10. R. Shiozaki, H. Gotoh and Y. Kera, Bull. Chem. Soc. Jpn., 66 (1993) 2790; R. Shiozaki, H. Kominami and Y. Kera, Synth. Commun., in press.
11. R.D. Peacock and T.J.R. Weakley, J. Chem. Soc. A, (1971) 1836.
12. J. Iball, J.N. Low and T.J.R. Weakley, J. Chem. Soc., Dalton Trans., (1974) 2021.
13. K. Nomiya, H. Murasaki and M. Miwa, Polyhedron, 4 (1985) 1793.
14. L.P. Kazanskii, A.M. Golubev, I.I. Baburina, E.A. Torchenkova and V.I. Spitsyn, Izv. Akad. Nauk SSSR Ser. Khim., (1978) 2215.
15. C. Rocchicciolini-Deltcheff, R. Thouvenot and M. Fouassier, Inorg. Chem., 21 (1982) 30; C. Rocchicciolini-Deltcheff, M. Fournier and R. Franck, Inorg. Chem., 22 (1983) 207.
16. C. Rocchicciolini-Deltcheff, R. Thouvenot and M. Fouassier, Inorg. Chem., 21 (1982) 30; C. Rocchicciolini-Deltcheff, M. Fournier and R. Franck, Inorg. Chem., 22 (1983) 207.
17. J. Owen and F.H.M. Thornley, Rep. Prog. Phys., 29 (1966) 676; R.M. Golding and T.P. Betteridge, J. Chem. Phys., 51 (1969) 2497.
18. J. Owen and F.H.M. Thornley, Rep. Prog. Phys., 29 (1966) 676; R.M. Golding and T.P. Betteridge, J. Chem. Phys., 51 (1969) 2497.
19. C. Kittel, Introduction to Solid State Physics, Wiley, 1966, 3rd edn., Chapter 14.
20. W.J. Moore, Physical Chemistry, Prentice-Hall, 1962, 3rd edn., Chapter 12.
21. N.E. Topp, Chemistry of the Rare-Earth Elements, Elsevier, 1965, Chapter 1.
22. J.H. Van Vleck, The Theory of Electric and Magnetic Susceptivities, Oxford University Press, London, 1992.