Polychlorinated materials as a source of polyanionic synthons

Tetrahedron

Volumn 52, Issue 5, 1996, Pages 1797-1810

  Guijarro, Albert ^a   Yus, Miguel ^a  

^a UNIVERSITY OF ALICANTE   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

ALKANEDIOL DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY; TECHNIQUE;

EID: 0030071426     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(95)01014-9     Document Type: Article

References (81)

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71. 26.
72. We thank a referee for calling our attention to this paper.
73. Another effect (electronic) to be considered comes from the fact that the more silyl groups atached to the carbanionic centre the less reactivity of the intermediate, so the more silylated carbanion is the more stable one.
74. In this case 10 mol % of DTBB was used as the catalyst.
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77. 4 as starting material the best yield was obtained by warm the reaction mixture till 0° before the hydrolysis step.
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79. 2O content measured gas-chromatographically) does not allow to determine D% content. Thus, calculated H/D% values are corrected considering this fact.
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