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c) For the synthesis of 7-deoxypancratistatin, see: Keck, G. E.; McHardy, S. F.; Murry, J. A. J. Am. Chem. Soc. 1995, 117, 7289-7290.
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19
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85031224944
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note
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1H NMR, selective decoupling experiments were used for stereochemical determinations.
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21
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0029034347
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Sajiki, H. Tetrahedron Lett. 1995, 36, 3465-3468. Loss of product was observed during purification process.
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Sajiki, H.1
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22
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85031216499
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note
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Alcohol 8 has been resolved by treatment with (-)-camphanic chloride and subsequent diastereomeric separation by column chromatography. Determination of the absolute configuration of each enantiomer is now under progress.
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