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All new compounds showed satisfactory spectroscopic, mass spectrometry and/or elemental analysis data.
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note
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The authors would like to thank Nicola Herbert of this department for performing this experiment.
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35
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0000682082
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The reduction of the ketene in 14 under the reaction conditions may be explained as follows: (matrix presented) For other examples of tributylstannyl enolate generation via tributylstannyl radical additions to carbonyl compounds, see: a) Enholm, E.J.; Xie, Y.; Abboud, K.A., J. Org. Chem., 1995, 60, 1112;
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85031225397
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note
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2, -20°C, 62%.
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