A P-O chelation with palladium: Toward understanding of the stereochemistry of an optically active sulfinyl-substituted phosphine with five stereogenic centres

Tetrahedron Asymmetry

Volumn 7, Issue 2, 1996, Pages 357-360

  Siah, Soh Yun ^a   Leung, Pak Hing ^a   Mok, K F ^a   Drew, Michael G B ^b  

^a NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

^b UNIVERSITY OF READING   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

7 PHOSPHABICYCLO[2.2.1]HEPT 2 ENE DERIVATIVE; NORBORNANE DERIVATIVE; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHELATION; CHIRALITY; DRUG STRUCTURE; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; X RAY CRYSTALLOGRAPHY;

EID: 0030059533     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/0957-4166(96)00005-5     Document Type: Article

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19. 0) of (-)-2: Pd-C(1), 1.969(5); Pd-N(12), 2.141(4); Pd-O(24), 2.160(4); Pd-P(14), 2.217(2); P(14)-C(18), 1.841(5); P(14)-C(15), 1.849(5); S(21)-O(24), 1.495(4); S(21)-C(22), 1.758(7); S(21)-C(20), 1.808(5); C(16)-C(17), 1.317(8); C(19)-C(20), 1.545(7); C(22)-C(23), 1.290(13); C(18)-P(14)-C(15), 81.1(2); C(17)-C(18)-C(19), 108.7(4); C(16)-C(15)-C(20), 105.7(4); C(17)-C(16)-C(15), 110.6(5), C(19)-C(20)-C(15), 105.1(4); C(15)-C(20)-S(21), 108.8(3); O(24)-S(21)-C(20), 109.9(2); S(21)-O(24)-Pd, 129.9(2); Pd-O(28)-S(21)-C(20), 17.1(4); O(24)-Pd-P(14)-C(15), -4.6(2); P(14)-C(15)-C(20)-S(21), -90.1(3).
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