Synthesis of pure enantiomers of a new diol ligand, trans-4,5-bis(2-hydroxyphenyl)-2,2-dimethyl-1,3-dioxolane

Tetrahedron Asymmetry

Volumn 7, Issue 1, 1996, Pages 149-155

  Yamamoto, Hidetoshi ^a   Kobayashi, Shigeru ^a   Kanemasa, Shuji ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

1,3 DIOXOLANE DERIVATIVE;

ARTICLE; DRUG PURIFICATION; DRUG SYNTHESIS; ENANTIOMER; PRIORITY JOURNAL; X RAY ANALYSIS;

EID: 0030058386     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/0957-4166(95)00431-9     Document Type: Article

References (23)

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2. "Handbook of Enantioselective Catalysis," Vol. 1 and 2, Ed. by Brunner, H.; Zettlemeier, W. VCH Publishers, Weinheim, 1993; "Catalytic Asymmetric Synthesis," Ed. by Ojima, I. VCH Publishers, New York, 1993; "Asymmetric Synthesis," Ed. by Aitken, R., A.; Kiléyi, S. N. Blackie A & P, Glasgow, 1992.
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4. Few diphosphine ligands form 9-membered chiral structures. See also Kagan, H. B. "Chiral Ligands for Asymmetric Catalysis," in "Asymmetric Synthesis," Ed. by Morrisom J. D. Vol. 5, Chap. 1, Academic Press, Florida, 1985.
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20. A catalytic amount of diol 1 can promote the reaction of diethylzinc with benzaldehyde to record a medium chiral induction (Yamamoto, H.; Kobayashi, S.; Kanemasa, S. unpublished result).
21. The authors deposited atomic coordinates for this structure with the Cambridge Crystallographic Data Centre. The coordinates can be obtained on request from The Director, Cambridge Crystallographic Data Centre, University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW, U.K.
22. Burla, M. C.; Camalli, M.; Cascarano, G.; Giacovazzo, G.; Polidori, G.; Spagna, R.; Viterbo, D. J. Appl. Crystallogr. 1989, 22, 389.
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