Kinetic resolution of racemic tricarbonyl(2-chloroanisole)chromium via palladium-catalysed asymmetric alkoxycarbonylation

Tetrahedron Letters

Volumn 37, Issue 2, 1996, Pages 167-170

  Carpentier, Jean François ^a   Pamart, Laurent ^a   Maciewjeski, Lucien ^a   Castanet, Yves ^a   Brocard, Jacques ^a   Mortreux, André ^a  

^a CNRS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

CHROMIUM DERIVATIVE; METAL COMPLEX;

ARTICLE; CHEMICAL REACTION KINETICS; COMPLEX FORMATION; ENANTIOMER;

EID: 0030049482     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(95)02117-5     Document Type: Article

References (11)

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2. (b) Carpentier, J.-F.; Petit, F.; Mortreux, A.; Dufaud, V.; Basset, J.-M.; Thivolle-Cazat, J. J. Mol. Catal. 1993, 81, 1-15. For recent publications, see also:
3. (c) Uemura, M.; Nishimura, H.; Hayashi, T. Tetrahedron Lett. 1993, 34, 107-110.
4. (d) Uemura, M.; Nishimura, H.; Kamikawa, K.; Nakayama, K.; Hayashi, Y. Tetrahedron Lett. 1994, 35, 1909-1912.
5. (e) Uemura, M.; Kamikawa, K. J. Chem. Soc., Chem. Commun. 1994, 2697-2698.
6. (f) Uemura, M.; Nishimura, H.; Kamikawa, K.; Shiro, M. Inorg. Chim. Acta 1994, 222, 63-70.
7. 2 system, carbonylation competed with nucleophilic aromatic substitution, a source of ethers, and a mixture of monocarbonylated-monosubstituted and disubstituted products was obtained. Carpentier, J.-F.; Castanet, Y.; Brocard, J.; Mortreux, A.; Petit, F. Tetrahedron Lett. 1992, 33,-2001-2004.
8. Carpentier, J.-F.; Finet, E.; Castanet, Y.; Brocard, J.; Mortreux, A. Tetrahedron Lett. 1994, 35, 4995-4998.
9. 3), 1719 (C=O).
10. The enantiomeric excess of chiral tricarbonyl(arene)chromium complexes was determined by HPLC as described in reference 4. Bitterwolf, T. E.; Hubler, T. L. J. Organomet. Chem. 1995, 487, 119-125.
11. Ozawa, F.; Kawasaki, N.; Okamoto, H.; Yamamoto, T.; Yamamoto, A. Organometallics 1987, 6, 1640.