On the triggering of free radical reactivity of dimethyldioxirane

Tetrahedron Letters

Volumn 37, Issue 2, 1996, Pages 249-252

  Curci, Ruggero ^a   Dinoi, Anna ^a   Fusco, Caterina ^a   Lillo, Maria A ^a  

^a UNIVERSITY OF BARI   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROPEROXIDE DERIVATIVE;

ARTICLE; CHEMICAL REACTION KINETICS; DRUG DEGRADATION; REACTION ANALYSIS;

EID: 0030044090     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(95)02140-X     Document Type: Article

References (21)

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3. (c) Adam, W.; Asensio, G.; Curci, R.; Gonzalès-Nuñez, M. E.; Mello, R. J. Org. Chem. 1992, 57, 953.
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7. For a recent review on dioxirane reactivity, see: Curci, R.; Dinoi, A.; Rubino, M. F. Pure Appl. Chem. 1995, 67 , 811. See references to the pertinent articles quoted therein.
8. For instance, see: C. L. Hill, in Advances in Oxygenated Processes; A. L. Baumstark, Ed.; JAI: Greenwich, CT, 1988; Vol. 1, Chapter 1, pp 1-30 and references therein.
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13. 3 are formed in detectable amounts.
14. o plot (data from entries 8-10) yields x = 1.5, as a preliminary rough estimate.
15. -1 has been estimated for DMDO decomposition at 25 °C: Hull, L. A.; Budhai, L. Tetrahedron Lett. 1993, 34, 5039.
16. 4, Molecular Sieves 5Å) dioxirane solutions.
17. For instance, see: (a) Edwards, J. O.; Gallopo, A. R.; McIsaac, J. E., Jr. J. Am. Chem. Soc. 1966, 88, 3891.
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19. Adam, W.; Asensio, G.; Curci, R.; Gonzalès-Nuñez, M. E.; Mello, R. , J. Am. Chem. Soc. 1992, 114, 7654.
20. Mello, R.; Ciminale, F.; Fiorentino, M.; Fusco, C.; Prencipe, T.; Curci, R. Tetrahedron Lett. 1990, 31, 6097.
21. Hamilton, G. A. in Molecular Mechanisms of Oxygen Activation; Hayashi, O., Ed.; Academic: New York, 1974; Chapter 10.