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7
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8944257301
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note
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-7 Torr).
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8
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8944219709
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note
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Film thicknesses were estimated by integrating the charge under the cyclic voltammetric wave corresponding to the oxidation of the ferrocene centers of a PVF film deposited onto a planar electrode of known area for the same time and conditions as that of the tip and substrate.
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12
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8944245450
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note
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Adhesion force calculations assume a force constant of 0.06 N/m, the published value for an unmodified, commercially available cantilever (Digital Instruments). The actual force constant of the modified tip is likely larger than the assumed value; therefore, emphasis is placed on the relative magnitudes of the adhesion forces.
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13
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0026896658
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(a) Ducker, W. A. Langmuir 1992, 8, 1831-1836.
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21
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8944228406
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note
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Carboxylate-terminated surfaces and methylene-terminated surfaces were prepared by immersing clean gold samples for 1 h in 5 mM solutions of 3-mercaptopropanoic acid and 1-hexanethiol in ethanol, respectively. Samples were thoroughly rinsed with ethanol and 0.05 M ethanolic KOH solution.
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