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19
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20
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3643084730
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Manuscript in preparation
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Froland, W. A.; Wilkinson, B., Priestley, N. D ; Morimoto, H.; Williams, P. G.; Lipscomb J. D., Floss, H. G. Manuscript in preparation.
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Froland, W.A.1
Wilkinson, B.2
Priestley, N.D.3
Morimoto, H.4
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Floss, H.G.7
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21
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85088542751
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note
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11 12
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22
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3643063827
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unpublished results
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Wilkinson, B., Liu, K. E., Valentine, A. M., Morimoto, H.; Williams, P G.; Lippard, S. J., Floss, H. G., unpublished results.
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Wilkinson, B.1
Liu, K.E.2
Valentine, A.M.3
Morimoto, H.4
Williams, P.G.5
Lippard, S.J.6
Floss, H.G.7
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23
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0029197421
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Newcomb, M.; Le Tadic-Biadatta, M.-H.; Chestney, D. L., Roberts, E S.; Hollenberg, P. F. J. Am. Chem. Soc. 1995, 117, 12085-12091.
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Newcomb, M.1
Le Tadic-Biadatta, M.-H.2
Chestney, D.L.3
Roberts, E.S.4
Hollenberg, P.F.5
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26
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0141613668
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Andres, H.; Morimoto, H., Williams, P. G. J. Chem. Soc., Chem. Commun. 1990, 627-628.
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Andres, H.1
Morimoto, H.2
Williams, P.G.3
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27
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3643146177
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note
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Incubations were performed for 12-15 mm at 45 °C in the presence of formaldehyde (5 μM) in 50 mM PIPES buffer, pH 7.1, total volume of 2.3 mL. Incubation with each isotopoiner was performed in duplicate.
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28
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3643123276
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note
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Calculation of the tritium distribution in the methyl/methylene/water positions based on unity and infinite isotope effects gives the range 3:2:1 to 3.1.0.
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29
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85088544907
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note
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3 was quantified by scintillation counting (0.04 μCi. 0 5% overall conversion) Incubation was performed in duplicate.
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31
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0014791003
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(a) Cornforth, J. W.; Redmond, J. W.; Eggerer, H.; Buckel, W.; Gutschow, C. Eur. J. Biochem. 1970, 14, 1-13.
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Cornforth, J.W.1
Redmond, J.W.2
Eggerer, H.3
Buckel, W.4
Gutschow, C.5
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32
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0014694549
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(b) Lüthy, J.; Retey, J.; Arigoni, D. Nature (London) 1969, 221, 1213-1215.
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Lüthy, J.1
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Arigoni, D.3
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34
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3643082660
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note
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24 of 26, corresponding to 82% ee S configuration, in close agreement with the optical purity of the starting material (88% ee).
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37
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3643116016
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note
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This finding cannot be explained by any kinetic resolution due to the observed further oxidation of an intermediate alkoxy species, since both enantiomers of the substrate give the same result.
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38
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3643068056
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note
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Such a phenomenon, considered very unlikely, was excluded in the studies with both sMMOs but could not be probed with the pMMO.
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39
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85088544571
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note
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-1 29
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40
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0029140873
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and references therein
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Newcomb, M.; Le Tadic, M.-H.; Putt, D. A.; Hollenberg, P. F. J. Am. Chem. Soc. 1995, 117, 3312-3313 and references therein.
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Newcomb, M.1
Le Tadic, M.-H.2
Putt, D.A.3
Hollenberg, P.F.4
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