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8944262770
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note
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w = 0.067) for 1967 absorption-corrected reflections with I > 3σ(I). Unresolvable disorder of the organic ligand prevented any detailed analysis of its geometry.
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15
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8944243482
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(a) Culter, A.; Raghu, S.; Rosenblum, M. J. Organomet. Chem. 1976, 108, 93.
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17
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8944258501
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note
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The assignments of the coordinated carbons α or β to the oxygenated substituent were determined through DEPT experiments, and the assignments for the respective protons were confirmed by proton-proton decoupling and HETCOR procedures.
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18
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8944230593
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Rappoport, Z. V. I., Ed.; J. Wiley & Sons: New York, Chapter 12
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19
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6444232720
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Stirling, C. J. M., Ed.; J. Wiley & Sons: New York, Chapter 1
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Theoretical calculations and experimental findings (synthesis of optically active sulfonium salt, and their crystal structure data) both confirm a pyramidal conformation for sulfonium salt. The barrier for inversion is calculated to be 24 kcal/mol with d orbitals and 13.5 kcal/mol without d orbitals. See: (a) Simonetta, M.; Gavezzotti, A. In The Chemistry of the Sulphonium Group; Stirling, C. J. M., Ed.; J. Wiley & Sons: New York, 1981; Part 1, Chapter 1, pp 1-14. (b) Andersen, K. K. Ibid.; Chapter 10.
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Simonetta, M.1
Gavezzotti, A.2
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0004205870
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Chapter 10
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Theoretical calculations and experimental findings (synthesis of optically active sulfonium salt, and their crystal structure data) both confirm a pyramidal conformation for sulfonium salt. The barrier for inversion is calculated to be 24 kcal/mol with d orbitals and 13.5 kcal/mol without d orbitals. See: (a) Simonetta, M.; Gavezzotti, A. In The Chemistry of the Sulphonium Group; Stirling, C. J. M., Ed.; J. Wiley & Sons: New York, 1981; Part 1, Chapter 1, pp 1-14. (b) Andersen, K. K. Ibid.; Chapter 10.
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The Chemistry of the Sulphonium Group
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Andersen, K.K.1
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21
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8944262769
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note
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This method of preparation for the vinylpyridinium complex 19 was found to be inferior to that reported in the Experimental Section.
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22
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0004205176
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Patai, S., Ed.; J. Wiley & Sons: New York, Chapter 2
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Fodor, G.1
Phillips, B.A.2
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8944241245
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Ph.D. Dissertation, Stanford University, Stanford, CA
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Harman, W. D. Ph.D. Dissertation, Stanford University, Stanford, CA, 1987.
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Harman, W.D.1
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25
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8944254180
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note
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π-bound olefin, ketone, and iminium complexes of pentaammineosmium(II) in every case documented show cis- and trans-ammine resonances separated by > 1 ppm.
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26
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0001029635
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Hodges, L. M.; Sabat, M.; Harman, W. D. Inorg. Chem. 1993, 32, 371.
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27
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8944236488
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note
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2-vinylacetate complex 14 with neat HOTf.
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28
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8944255093
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note
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CH = 7.9 Hz.
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31
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0001264675
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37
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8944246263
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note
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HH = 10.7 Hz).
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39
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8944248703
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note
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3).
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40
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0000884941
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Patai, S., Ed.; J. Wiley & Sons: New York, Chapter 9
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(a) Neilson, D. G. In The Chemistry of Amidines and Imidates; Patai, S., Ed.; J. Wiley & Sons: New York, 1975; Chapter 9, pp 389-412.
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0002799168
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8944243481
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8944222510
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8944241244
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2-allene from 33 resulted in intractable mixtures.
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