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The microbial reduction of α′-bromo-α,α,α-trifluoroketones analogous to 1a,b has also been studied due to the high synthetic versatility of the corresponding bromo-alcohols. However, in our hands while the carbonyl substrates disappeared from the cultural medium, no desired α′-bromo-α,α,α-trifluoroalcohols were recovered.
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