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A tautomer of 26 could be also considered. Although we have no mechanistic evidence, tentatively the formation of compound 26 (which is independent from the presence of products 17 or 24) could be explained by assuming the N-benzoyl-N′-phenylcarbodiimide as a reasonable photolytic intermediate. However, whether the migration of the phenyl moiety of the benzoyl group at the carbodiimidic carbon atom will precede or follow the involvement of methylamine remains questionable.
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