메뉴 건너뛰기




Volumn 118, Issue 28, 1996, Pages 6786-6787

Intramolecular microsolvation of thermoneutral gas-phase S(N)2 reactions

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CHEMICAL REACTION KINETICS; DRUG STABILITY; IONIZATION; SOLUBILIZATION; STRUCTURE ACTIVITY RELATION;

EID: 0029990508     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953586b     Document Type: Article
Times cited : (22)

References (31)
  • 1
    • 0010024509 scopus 로고
    • Almoster Ferreira, M. A., Ed.; D. Reidel Publishing Co.: Dordrecht
    • Bohme, D. K. Ionic Processes in the Gas Phase; Almoster Ferreira, M. A., Ed.; D. Reidel Publishing Co.: Dordrecht, 1984; Vol. 118.
    • (1984) Ionic Processes in the Gas Phase , vol.118
    • Bohme, D.K.1
  • 10
    • 8944259500 scopus 로고    scopus 로고
    • note
    • In addition to the transition state, the ion-molecule complex will also be stabilized relative to the unsolvated system. The stability of the collision complex, however, is incidental to the observed reaction efficiency.
  • 13
    • 0012459682 scopus 로고
    • Standard Reference Database 19B; National Institute of Standards and Technology: Gaithersberg, MD
    • Bartmess, J. E. NIST Negative Ion Energetics Database, Version 3.0; Standard Reference Database 19B; National Institute of Standards and Technology: Gaithersberg, MD, 1993.
    • (1993) NIST Negative Ion Energetics Database, Version 3.0
    • Bartmess, J.E.1
  • 19
    • 8944232159 scopus 로고    scopus 로고
    • note
    • We have found no other thermodynamically allowed mechanism for the exchange of chloride ion. Elimination and anion-mediated isomerizations are both endothermic and endergonic.
  • 23
    • 8944258173 scopus 로고    scopus 로고
    • note
    • The nature of induction is still a topic of considerable debate (see refs 24 and 25). For purposes of this paper, we use induction to refer only to those effects which are mediated by the σ bond framework of a molecule.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.