Valence electron cloud asymmetry from two points of view: A correlation between Mössbauer quadrupole splittings and 57Fe NMR chemical shifts of diamagnetic iron(II) porphyrinates

Journal of the American Chemical Society

Volumn 118, Issue 22, 1996, Pages 5272-5276

  Polam, Jayapal Reddy ^a   Wright, Joshua L ^a   Christensen, Kenner A ^a   Walker, F Ann ^a   Flint, Holger ^b   Winkler, Heiner ^b   Grodricki, Michael ^b   Trautwein, Alfred X ^b  

^a University of Arizona ^*  (United States)

^b UNIVERSITY OF LÜBECK   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CYTOCHROME C; FERROUS ION; OCTAETHYLPORPHINE; PORPHYRIN; TETRAMESITYLPORPHYRIN; UNCLASSIFIED DRUG;

ANISOTROPY; ARTICLE; CHEMICAL STRUCTURE; MOSSBAUER SPECTROSCOPY; PROTON NUCLEAR MAGNETIC RESONANCE; TEMPERATURE DEPENDENCE;

EID: 0029977389     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja954096m     Document Type: Article

References (41)

1. Mink, L. M.; Christensen, K. A.; Walker, F. A. J. Am. Chem. Soc. 1992, 114, 6930.
2. Mink, L. M.; Polam, J. R.; Christensen, K. A.; Bruck, M. A.; Walker, F. A. J. Am. Chem. Soc. 1995, 117, 9329-9339.
3. Houlton, A.; Miller, J. R.; Roberts, M. G.; Silver, J. J. Chem. Soc., Dalton Trans. 1991, 467.
4. Connor, W. M.; Straub, D. K. Inorg. Chem. 1976, 15, 2289.
5. Collman, J. P.; Gagne, R. R.; Reed, C. A.; Halbert, T. R.; Lang, G.; Robinson, W. T. J. Am. Chem. Soc. 1975, 97, 1427.
6. Straub, D. K.; Connor, W. M. Ann. N. Y. Acad. Sci. 1973, 206, 383.
7. Kobayashi, H.; Maeda, Y.; Yanagawa, Y. Bull. Chem. Soc. Jpn. 1970, 43, 2342.
8. Sams, J. R.; Tsin, T. B. In The Porphyrins; Dolphin, D., Ed.; Academic Press: New York, 1979; Vol. 4, p 425.
9. Lang, G.; Herbert, D.; Yonetani, T. J. Chem. Phys. 1968, 49, 944.
10. Maeda, Y.; Harami, T.; Morita, Y., Ttautwein, A.; Gonser, U. J. Chem. Phys. 1981, 75, 36.
11. Nozawa, T.; Sato, M.; Hatano, M.; Kobayashi, N.; Osa, T. Chem. Lett. 1983, 1289.
12. Baltzer, L.; Becker, E. D.; Averill, B. A.; Hutchinson, J. M.; Gansow, O. J. Am. Chem. Soc. 1984, 106, 2444.
13. Baltzer, L.; Landergren, M. J. Chem. Soc., Chem. Commun. 1987, 32.
14. Baltzer, L.; Landergren, M. J. Am. Chem. Soc. 1990, 112, 2804.
15. (a) La Mar, G. N.; Viscio, D. B.; Budd, D. L.; Gersonde, K. Biochem. Biophys. Res. Commun. 1978, 82, 19.
16. (b) La Mar, G. N.; Dellinger, C. M.; Sankar, S. S. Biochem. Biophys. Res. Commun. 1985, 128, 628.
17. Lee, H. C.; Gard, J. K.; Brown, T. L.; Oldfield, E. J. Am. Chem. Soc. 1985, 107, 4087.
18. Baltzer, L.; Becker, E. D.; Tschudin, R. G.; Gansow, O. A. J. Chem. Soc., Chem. Commun. 1985, 1040.
19. Schwenck, A. J. Magn. Reson. 1971, 5, 376.
20. Baltzer, L. J. Am. Chem. Soc. 1987, 109, 3479.
21. Münck, E. Methods Enzymol. 1974, 54, 372.
22. 2 = 5.5).
23. Nesset, M. J. M.; Shokhirev, N. V.; Enemark, P. D.; Jacobson, S. E.; Walker, F. A. Submitted for publication.
24. Chung, J.; Lee, H. C.; Oldfield, E. J. Magn. Reson. 1990, 90, 148-157.
25. (a) Bancroft, G. M.; Mays, M. J.; Prater, B. E. J. Chem. Soc. A 1970, 956.
26. (b) Bancroft, G. M.; Platt, R. H. Adv. Inorg. Chem. Radiochem. 1972, 15, 59.
27. (a) Grodzicki, M.; Manning, V.; Trautwein, A. X.; Friedt, J. M. J. Phys. B: At. Mol. Phys. 1987, 20, 5595.
28. (b) Paulsen, H.; Ding, X.-Q.; Grodzicki, M.; Butzlaff, Ch.; Trautwein, A. X.; Hartung, R.; Wieghardt, K. Chem. Phys. 1994, 184, 149.
29. (c) Paulsen, H.; Krockel, M.; Grodzicki, M.; Bill, E.; Trautwein, A. X.; Leigh, J. J.; Silver, J. Inorg. Chem. 1995, 34, 6211.
30. Laszlo, P. In NMR of Newly Accessible Nuclei; Laszlo, P., Ed.; Academic Press: New York, 1983; Vol. 2. pp 259-266.
31. (a) Griffith, J. S.; Orgel, L. E. Trans. Faraday Soc. 1957, 53, 601.
32. (b) Juranic, N.; Celap, M. B.; Vucelic, D.; Malinar, M. J.; Radivojsa, P. N. J. Magn. Reson. 1979, 35, 319.
33. (c) Juranic, N. Coord. Chem. Rev. 1989, 96, 253.
34. Scheldt, W. R.; Chipman, D. M. J. Am. Chem. Soc. 1986, 108, 1163.
35. Houlton, A.; Miller, J. R.; Roberts, R. M. G.; Silver, J. J. Chem. Soc., Dalton Trans. 1990, 2181.
36. Momot, K. I. Unpublished work.
37. Chemical shift for protoporphyrin IX complex.
38. This work.
39. Chemical shift for TPP complex.
40. Chemical shift for TMP complex.
41. Chemical shift corrected for the difference between TMP and OEP, ∼250 ppm.