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25
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33646438683
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note
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It is assumed that the 2,2′-dimethyl-6,6′-dinitrobiphenyl group is conformationally rigid. The calculated energy profile (AMI) for 360° rotation about the central bond of the atropisomeric biphenyl is steep and shows a single pair of symmetry-related energy minima at dihedral angles approaching 90° and 270°, with a rotational barrier of ca. 35 kcal/mol.
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26
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0000546092
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Atropisomeric dopants have been reported on several occasions to induce a cholesteric phase in nematic liquid crystal hosts. For recent examples, see: (a) Gottarelli, G.; Proni, G.; Spada, G. P.; Fabbri, D.; Gladiali, S.; Rosini, C. J. Org. Chem. 1996, 61, 2013, and references cited therein.
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Gottarelli, G.1
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Fabbri, D.4
Gladiali, S.5
Rosini, C.6
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33646451964
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Wavefunction, Inc., 18401 Von Karmann, #210, Irvine, CA
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Wavefunction, Inc., 18401 Von Karmann, #210, Irvine, CA.
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