Hammett studies on alkene extrusion from rhenium(V)diolates and an MO description of metal alkoxide-alkyl metal oxo interconversion

Journal of the American Chemical Society

Volumn 118, Issue 11, 1996, Pages 2625-2633

  Gable, Kevin P ^a   Juliette, Jerrick J J ^a  

^a OREGON STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENE DERIVATIVE; RHENIUM COMPLEX;

ARTICLE; CALCULATION; DRUG STRUCTURE; DRUG SYNTHESIS; MOLECULAR DYNAMICS; THEORY;

EID: 0029960794     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja952537w     Document Type: Article

References (72)

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38. It is, however, important to note the differences between this system and organic processes as has been done above The absence of charge means that electronic effects will be dictated by changes in electronegativity Thus, migration of carbon from (electronegative) oxgen to (electropositive) rhenium will result in the positive ρ seen here rather than the negative value seen in the organic processes cited.
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47. This is a well-documented process, particularly for early metal oxo compounds. See: (a) deWith, J.; Horton, A. D.; Orpen, A. G. Organometallics 1993, 12, 1493-1496. (b) Klein, D. P.; Hayes, J. C.; Bergman, R. G. J Am. Chem. Soc. 1988, 110, 3704-3706. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079-3080. (d) Hartwig, J. F ; Bergman, R. G.; Anderson, R. A. J. Am. Chem. Soc. 1990, 112, 3234-3236. (e) Carney, M. J.; Walsh, P. J.; Hollander, F. J., Bergman, R G. J. Am. Chem. Soc. 1990, 112, 6426-6428. (f) Vaughan, G. A.; Sofield, C D., Hillhouse, G. L.; Rheingold, A. L. J Am. Chem. Soc. 1989, 111, 5491-5493. (g) Walsh, P. J.; Baranger, A. M., Bergman, R. G. J. Am Chem. Soc 1992, 114, 1708-1719. (h) Baranger, A. M.; Walsh, P. J.; Bergman, R. G. J. Am Chem. Soc. 1993, 115, 2753-2763.
48. This is a well-documented process, particularly for early metal oxo compounds. See: (a) deWith, J.; Horton, A. D.; Orpen, A. G. Organometallics 1993, 12, 1493-1496. (b) Klein, D. P.; Hayes, J. C.; Bergman, R. G. J Am. Chem. Soc. 1988, 110, 3704-3706. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079-3080. (d) Hartwig, J. F ; Bergman, R. G.; Anderson, R. A. J. Am. Chem. Soc. 1990, 112, 3234-3236. (e) Carney, M. J.; Walsh, P. J.; Hollander, F. J., Bergman, R G. J. Am. Chem. Soc. 1990, 112, 6426-6428. (f) Vaughan, G. A.; Sofield, C D., Hillhouse, G. L.; Rheingold, A. L. J Am. Chem. Soc. 1989, 111, 5491-5493. (g) Walsh, P. J.; Baranger, A. M., Bergman, R. G. J. Am Chem. Soc 1992, 114, 1708-1719. (h) Baranger, A. M.; Walsh, P. J.; Bergman, R. G. J. Am Chem. Soc. 1993, 115, 2753-2763.
49. This is a well-documented process, particularly for early metal oxo compounds. See: (a) deWith, J.; Horton, A. D.; Orpen, A. G. Organometallics 1993, 12, 1493-1496. (b) Klein, D. P.; Hayes, J. C.; Bergman, R. G. J Am. Chem. Soc. 1988, 110, 3704-3706. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079-3080. (d) Hartwig, J. F ; Bergman, R. G.; Anderson, R. A. J. Am. Chem. Soc. 1990, 112, 3234-3236. (e) Carney, M. J.; Walsh, P. J.; Hollander, F. J., Bergman, R G. J. Am. Chem. Soc. 1990, 112, 6426-6428. (f) Vaughan, G. A.; Sofield, C D., Hillhouse, G. L.; Rheingold, A. L. J Am. Chem. Soc. 1989, 111, 5491-5493. (g) Walsh, P. J.; Baranger, A. M., Bergman, R. G. J. Am Chem. Soc 1992, 114, 1708-1719. (h) Baranger, A. M.; Walsh, P. J.; Bergman, R. G. J. Am Chem. Soc. 1993, 115, 2753-2763.
50. This is a well-documented process, particularly for early metal oxo compounds. See: (a) deWith, J.; Horton, A. D.; Orpen, A. G. Organometallics 1993, 12, 1493-1496. (b) Klein, D. P.; Hayes, J. C.; Bergman, R. G. J Am. Chem. Soc. 1988, 110, 3704-3706. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079-3080. (d) Hartwig, J. F ; Bergman, R. G.; Anderson, R. A. J. Am. Chem. Soc. 1990, 112, 3234-3236. (e) Carney, M. J.; Walsh, P. J.; Hollander, F. J., Bergman, R G. J. Am. Chem. Soc. 1990, 112, 6426-6428. (f) Vaughan, G. A.; Sofield, C D., Hillhouse, G. L.; Rheingold, A. L. J Am. Chem. Soc. 1989, 111, 5491-5493. (g) Walsh, P. J.; Baranger, A. M., Bergman, R. G. J. Am Chem. Soc 1992, 114, 1708-1719. (h) Baranger, A. M.; Walsh, P. J.; Bergman, R. G. J. Am Chem. Soc. 1993, 115, 2753-2763.
51. This is a well-documented process, particularly for early metal oxo compounds. See: (a) deWith, J.; Horton, A. D.; Orpen, A. G. Organometallics 1993, 12, 1493-1496. (b) Klein, D. P.; Hayes, J. C.; Bergman, R. G. J Am. Chem. Soc. 1988, 110, 3704-3706. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079-3080. (d) Hartwig, J. F ; Bergman, R. G.; Anderson, R. A. J. Am. Chem. Soc. 1990, 112, 3234-3236. (e) Carney, M. J.; Walsh, P. J.; Hollander, F. J., Bergman, R G. J. Am. Chem. Soc. 1990, 112, 6426-6428. (f) Vaughan, G. A.; Sofield, C D., Hillhouse, G. L.; Rheingold, A. L. J Am. Chem. Soc. 1989, 111, 5491-5493. (g) Walsh, P. J.; Baranger, A. M., Bergman, R. G. J. Am Chem. Soc 1992, 114, 1708-1719. (h) Baranger, A. M.; Walsh, P. J.; Bergman, R. G. J. Am Chem. Soc. 1993, 115, 2753-2763.
52. This is a well-documented process, particularly for early metal oxo compounds. See: (a) deWith, J.; Horton, A. D.; Orpen, A. G. Organometallics 1993, 12, 1493-1496. (b) Klein, D. P.; Hayes, J. C.; Bergman, R. G. J Am. Chem. Soc. 1988, 110, 3704-3706. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079-3080. (d) Hartwig, J. F ; Bergman, R. G.; Anderson, R. A. J. Am. Chem. Soc. 1990, 112, 3234-3236. (e) Carney, M. J.; Walsh, P. J.; Hollander, F. J., Bergman, R G. J. Am. Chem. Soc. 1990, 112, 6426-6428. (f) Vaughan, G. A.; Sofield, C D., Hillhouse, G. L.; Rheingold, A. L. J Am. Chem. Soc. 1989, 111, 5491-5493. (g) Walsh, P. J.; Baranger, A. M., Bergman, R. G. J. Am Chem. Soc 1992, 114, 1708-1719. (h) Baranger, A. M.; Walsh, P. J.; Bergman, R. G. J. Am Chem. Soc. 1993, 115, 2753-2763.
53. This is a well-documented process, particularly for early metal oxo compounds. See: (a) deWith, J.; Horton, A. D.; Orpen, A. G. Organometallics 1993, 12, 1493-1496. (b) Klein, D. P.; Hayes, J. C.; Bergman, R. G. J Am. Chem. Soc. 1988, 110, 3704-3706. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079-3080. (d) Hartwig, J. F ; Bergman, R. G.; Anderson, R. A. J. Am. Chem. Soc. 1990, 112, 3234-3236. (e) Carney, M. J.; Walsh, P. J.; Hollander, F. J., Bergman, R G. J. Am. Chem. Soc. 1990, 112, 6426-6428. (f) Vaughan, G. A.; Sofield, C D., Hillhouse, G. L.; Rheingold, A. L. J Am. Chem. Soc. 1989, 111, 5491-5493. (g) Walsh, P. J.; Baranger, A. M., Bergman, R. G. J. Am Chem. Soc 1992, 114, 1708-1719. (h) Baranger, A. M.; Walsh, P. J.; Bergman, R. G. J. Am Chem. Soc. 1993, 115, 2753-2763.
54. This is a well-documented process, particularly for early metal oxo compounds. See: (a) deWith, J.; Horton, A. D.; Orpen, A. G. Organometallics 1993, 12, 1493-1496. (b) Klein, D. P.; Hayes, J. C.; Bergman, R. G. J Am. Chem. Soc. 1988, 110, 3704-3706. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079-3080. (d) Hartwig, J. F ; Bergman, R. G.; Anderson, R. A. J. Am. Chem. Soc. 1990, 112, 3234-3236. (e) Carney, M. J.; Walsh, P. J.; Hollander, F. J., Bergman, R G. J. Am. Chem. Soc. 1990, 112, 6426-6428. (f) Vaughan, G. A.; Sofield, C D., Hillhouse, G. L.; Rheingold, A. L. J Am. Chem. Soc. 1989, 111, 5491-5493. (g) Walsh, P. J.; Baranger, A. M., Bergman, R. G. J. Am Chem. Soc 1992, 114, 1708-1719. (h) Baranger, A. M.; Walsh, P. J.; Bergman, R. G. J. Am Chem. Soc. 1993, 115, 2753-2763.
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