Convenient preparation of a cyclopropanation reagent: α-Siloxymethyliron complex

Synthetic Communications

Volumn 26, Issue 7, 1996, Pages 1371-1377

  Du, Hong ^a   Yang, Fukang ^a   Mahmun Hossain, M ^a  

^a UNIVERSITY OF WISCONSIN MILWAUKEE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CYCLOPROPANE DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0029959009     PISSN: 00397911     EISSN: None     Source Type: Journal    
DOI: 10.1080/00397919608003498     Document Type: Article

References (9)

1. Vargas, R. M.; Theys, R. T.; Hossain, M. M. J. Am. Chem. Soc. 1992, 114, 777.
2. 4- for cyclopropanation and was reported by Helquist.a) O'Connor, E. J.; Brandt, S.; Helquist, P J. Am. Chem. Soc. 1987, 109, 3739.
3. b) Mattson, M. N.; Bays, J. P.; Zakutansky, J.; Stolarski; V.; Helquist, P. J. Org. Chem. 1989, 54, 2467. Another, less frequently used, technique utilizes Fp anion and α-chloromethyl methyl ether (extremely toxic) to produce α-methoxymethyliron complex.
4. c) Jolly, P. W.; Pettit, R. J. Am. Chem. Soc. 1955, 88, 5044.
5. d) Riley, P. E.; Capshew, C. E.; Pettit, R.; Davis, R. E. Inorg. Chem. 1978, 17, 408.
6. a) Jung, M. E.; Mossman, A. B. ; Lyster, M. A. J. Org. Chem. 1978, 43, 3698.
7. b) Brinkman, K. C.; Vaughn G. D.; Gladysz, J. A. Organometallics 1982, 1, 1056.
8. a) Brookhart, M.; Humphrey, M. B.; Kratzer, H. J.; Nelson, G. O. J. Am. Chem. Soc. 1980, 102, 7802.
9. b) Quellette, R. J.; Robins, R. D.; South, Jr. A. J. Am. Chem. Soc. 1968, 90, 1619.