Gas-phase basicity and heat of formation of sulfine CH2=S=O

Journal of the American Chemical Society

Volumn 118, Issue 27, 1996, Pages 6516-6517

  Bouchoux, G ^a   Salpin, J Y ^a  

^a LABORATOIRE HÉTÉROÉLÉMENTS ET COORDINATION   (France)

Author keywords

[No Author keywords available]

Indexed keywords

SULFOXIDE;

ARTICLE; DRUG SYNTHESIS; THERMODYNAMICS;

EID: 0029946065     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9610601     Document Type: Article

References (22)

1. Zha, Q.; Nishimura, T.; Meiseis, G. G. Int. J. Mass Spectrom. Ion Process 1988, 83, 1.
2. Ruttink, P. J. A.; Francis, J. T.; Burgers, P. C.; Terlouw, J. K. J. Phys. Chem., in press.
3. Block, E.; Penn, R. E.; Olsen, R. J.; Sherwin, P. F. J. Am. Chem. Soc. 1976, 98, 1264.
4. Block, E.; Bock, H.; Mohmand, S.; Rosmus, P.; Solouki, B. Angew. Chem., Int. Ed. Engl. 1976, 15, 383.
5. Gozzo, F. C.; Eberlin, M. N. J. Mass Spectrom. 1995, 30, 1553.
6. Ruttink, P. J. A.; Burgers, P. C.; Terlouw, J. K. Chem. Phys. Lett. 1994, 229, 495.
7. Turecek, F. J. Phys. Chem. 1994, 98, 3701.
8. (a) Bouchoux, G.; Salpin, J. Y.; Leblanc, D. Int. J. Mass Spectrom. Ion Process 1996, 153, 37.
9. (b) Bouchoux, G.; Salpin, J. Y. Submitted for publication in J. Phys. Chem.
10. Turecek, F.; Drinkwater, D. E.; McLafferty, F. W. J. Am. Chem. Soc. 1989, 111, 7696.
11. McGibbon, G. A.; Burgers, P. C.; Terlouw, J. K. Chem. Phys. Lett. 1994, 218, 499.
12. The CA mass spectrum of m/z 63 ions generated from tetramethylene sulfine has been obtained using the mass-analyzed ion kinetic energy (MIKE) technique on a VG-ZAB-2F mass spectrometer of B-E geometry (accelerating voltage: 8 kV; target gas: He). The most significant peaks (m/z, percent) are the following: 62, 39; 61, 30; 49, 81; 48, 69; 46, 1650; 45, 3030; 44, 1360; 34, 30; 33, 73; 32, 95; 31, 100; 29, 74; 17, 9; 15, 10; 14, 30; 13, 16; 12. 17 (the signals at m/z 61, 46, and 45 were not chosen for normalizing the ion abundances because they are also coming from unimolecular processes).
13. Su, T.; Bowers, M. T. In Gas-Phase Ion Chemistry; Bowers, M. T., Ed.; Academic Press: New York, 1979; Vol. 1, Chapter 3.
14. Szulejko, J. E.; McMahon, T. B. J. Am. Chem. Soc. 1993, 115, 7839.
15. Lias, S. G.; Bartmess, J. E.; Liebman, J. F.; Holmes, J. H.; Levin, R. D.; Mallard, W. G. J. Phys. Chem. Ref. Data, Suppl. 1 1988, 17.
16. Benson, S. W. Chem. Rev. 1978, 78, 123.
17. Miller, K. J. J. Am. Chem. Soc. 1990, 112, 8533.
18. Clellan, A. C.; Freeman, W. H. Table of Experimental Dipole Moments; Freeman: San Francisco, CA, 1963; Vol. 1; Rahara Ent.: E1 Cerrito. 1973; Vol. 2.
19. Clellan, A. C.; Freeman, W. H. Table of Experimental Dipole Moments; Freeman: San Francisco, CA, 1963; Vol. 1; Rahara Ent.: E1 Cerrito. 1973; Vol. 2.
20. Bouchoux, G.; Drancourt, D.; Leblanc, D.; Yanez, M.; Mo. O. New J. Chem. 1995, 19, 1243.
21. Dewar, M. J. S.; Zoebisch, E. G.; Healy, E. F.; Stewart, J. J. P. J. Am. Chem. Soc. 1992, 107, 3902.
22. Traeger, J. C. Rapid Commun. Mass Spectrom. 1996, 10, 119.