Reductively induced dimerization of the ligated benzene in [Mn(η6-C6H6)(CO)3]+: Formation of the initial C-C bond by anion/cation addition

Journal of the American Chemical Society

Volumn 118, Issue 17, 1996, Pages 4190-4191

  Lee, Sijoon ^a   Lovelace, Sherri R ^a   Arford, Debra J ^a   Geib, Steven J ^a   Weber, Stephen G ^a   John Cooper, N ^a  

^a UNIVERSITY OF PITTSBURGH   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BENZENE DERIVATIVE;

ARTICLE; CYCLIC POTENTIOMETRY; DIMERIZATION; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 0029944003     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja952217c     Document Type: Article

References (25)

1. Thompson, R. L.; Geib, S. J.; Cooper, S. J. Am. Chem. Soc. 1991, 113, 8961.
2. (a) Nesmayanov, A. N.; Denisovich, L. I : Gubin, S. P.; Vol'kenau, N. A.; Sirotkina,E. I.; Bolesova, I. -N. J. Organomet. Chem. 1969, 20, 169.
3. (b) Nesmayanov, A. N.; Vol'kenau, N. A.; Shilovtseva, L. S.; Petrakova, V. A. J. Organomet. Chem. 1973, 61, 329.
4. (c) Nesmayanov, A. N.; Vol'kenau, N. A.; Petrakova, V. A. J. Organomet. Chem. 1977, 136, 363.
5. (a) Hamon, J.-R.; Astruc, D.; Michaud, P. J. Am. Chem. Soc. 1981, 103, 758.
6. (b) Rasjasekharan, M. V.; Giezynski, S.; Ammeter, J. H.; Oswald, N.; Michaud, P.; Hamon, J.-R.; Astruc, D. J. Am. Chem. Soc. 1982, 104. 2400.
7. (c) Astruc, D. Chem. Rev: 1988, 88, 1189.
8. Thompson, R. L.; Lee, S.; Rheingold, A. L.; Cooper, N. J Organometallics 1991, 10, 1657.
9. wRF = 3.32%. with GOF = 0.80. Details will be published elsewhere.
10. 8
11. Andrianov, V. G.; Struchkov, Yu. T.; Petrakova, V. A.; Vol'kenau, N. A. Koord. Khim. 1986, 12, 978.
12. Gaudet, M. V.; Hanson, A. W.; White, P. S.; Zaworotko, M. J. Organometallics 1989, 8, 286.
13. Bard, A. J., Faulkner, L. R. Electrochemical Methods; Wiley: New York, 1980.
14. For leading references, see: (a) Rieke; R. D.; Henry, W. P.; Arney, J. S. Inorg. Chem. 1987, 26, 420. (b) Finke, R. G.; Voegeli, R. H.; Laganis, E. D.; Boekelheidi, V. Organometallics 1983, 2, 347. (c) Plitzko, K.-D.; Wehrle, G.; Gollas, B.; Rapko, B.; Dannheim, J.; Boekelheidi, V. J. Am. Chem. Soc. 1990, 112, 6556. Pierce, D. T.; Geiser, W. E. J. Am. Chem. Soc. 1992, 114, 6063.
15. For leading references, see: (a) Rieke; R. D.; Henry, W. P.; Arney, J. S. Inorg. Chem. 1987, 26, 420. (b) Finke, R. G.; Voegeli, R. H.; Laganis, E. D.; Boekelheidi, V. Organometallics 1983, 2, 347. (c) Plitzko, K.-D.; Wehrle, G.; Gollas, B.; Rapko, B.; Dannheim, J.; Boekelheidi, V. J. Am. Chem. Soc. 1990, 112, 6556. Pierce, D. T.; Geiser, W. E. J. Am. Chem. Soc. 1992, 114, 6063.
16. For leading references, see: (a) Rieke; R. D.; Henry, W. P.; Arney, J. S. Inorg. Chem. 1987, 26, 420. (b) Finke, R. G.; Voegeli, R. H.; Laganis, E. D.; Boekelheidi, V. Organometallics 1983, 2, 347. (c) Plitzko, K.-D.; Wehrle, G.; Gollas, B.; Rapko, B.; Dannheim, J.; Boekelheidi, V. J. Am. Chem. Soc. 1990, 112, 6556. Pierce, D. T.; Geiser, W. E. J. Am. Chem. Soc. 1992, 114, 6063.
17. For leading references, see: (a) Rieke; R. D.; Henry, W. P.; Arney, J. S. Inorg. Chem. 1987, 26, 420. (b) Finke, R. G.; Voegeli, R. H.; Laganis, E. D.; Boekelheidi, V. Organometallics 1983, 2, 347. (c) Plitzko, K.-D.; Wehrle, G.; Gollas, B.; Rapko, B.; Dannheim, J.; Boekelheidi, V. J. Am. Chem. Soc. 1990, 112, 6556. Pierce, D. T.; Geiser, W. E. J. Am. Chem. Soc. 1992, 114, 6063.
18. (a) Treichel, P. M. In Comprehensive Organometallic Chemistry; Wilkinson, G., Stone, F. G. A., Abel, E. W., Eds.; Pergamon: Oxford, 1982; Vol. 4, Chapter 29.
19. (b) Semmelhack, M. F. In Comprehensive Organic Synthesis, Trost, B. M., Fleming, I., Eds.; Pergamon: Oxford, 1991; Vol. 4, Chapter 2.4.
20. * elimination peaks were summed to calculate isotopic distributions.
21. 12-3.
22. Dual pathways might reflect the need for a particular orientation of the ions if a collision is to result in C-C bond formation.
23. (a) Lehmann, R E.; Bockman, T. M.; Kochi, J. K. J. Am. Chem. Soc. 1990, 112, 458.
24. (b) Lehmann, R. E.; Kochi, J. K. Organometallics 1991, 10, 190.
25. Yabe, T.; Kochi, J. K. J Am. Chem. Soc. 1992, 114, 4491.