Synthesis and characterization of [η4-P7Ni(CO)]3- [η4-HP7Ni(CO)]2-, and [η2-P7PtH(PPh3)]2-: Two electronically equivalent protonated zintl ion complexes with markedly different structures

Journal of the American Chemical Society

Volumn 118, Issue 19, 1996, Pages 4713-4714

  Charles, Scott ^a   Fettmger, James C ^a   Bott, Simon G ^b   Eichhorn, Bryan W ^a  

^a Bldg 142   (United States)

^b UNIVERSITY OF NORTH TEXAS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

PLATINUM COMPLEX;

ARTICLE; DRUG STRUCTURE; INFRARED SPECTROPHOTOMETRY; X RAY CRYSTALLOGRAPHY;

EID: 0029942919     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953963k     Document Type: Article

References (27)

1. Eichhorn, B. W.; Haushalter, R. C.; Huffman, J. C. Angew. Chem., Int. Ed. Engl. 1989, 28, 1032.
2. Charles, S.; Bott, S. G.; Rheingold, A. L.; Eichhorn, B. W J. Am. Chem. Soc. 1994, 116, 8077.
3. Bolle, U.; Tremel, W. J. Chem. Soc., Chem. Commun. 1994, 217.
4. (a) von Schnering, H. G. Angew. Chem., Int. Ed. Engl. 1981, 20, 33.
5. (b) von Schcering, H. G.; Hönle, W. Chem. Rev. 1988, 88, 243.
6. (c) Corbett, J. D. Chem. Rev. 1985, 85, 383.
7. (d) von Schnering, H. G. In Rings. Chains, and Macromolecules of Main Group Elements; Rheingoid, A. L., Ed.; Eisevier: Amsterdam, 1977.
8. (a) Charles, S.; Fettinger, J. C.; Eichhorn, B. W. Inorg. Chem. 1996, 35, 1540.
9. (b) Charles, S.; Fettinger, J. C.; Eichhorn, B. W. To be published.
10. Charles, S.; Fetringer, J. C.; Eichhorn, B. W J. Am. Chem. Soc. 1995, 117, 5303.
11. Charles, S.; Eichhorn. B. W.; Bott, S. G. J. Am. Chem. Soc. 1993, 115, 5837.
12. 2Jc-P = 8.5 Hz).
13. (a) Cheng, P.-T., Cook, C. D.; Koo, C. H.; Nyburg, S. C., Shiomi, M. T. Acta Crysiallogr. 1971, 27B, 1904.
14. (b) Kruger, C.; Tsay, Y.-H. Cryst. Struct. Commun. 1974, 3, 455.
15. (c) Pickardt, J. v.; Rosch, L.; Schumann, H. Z. Anorg. Allg. Chem. 1976, 426, 66.
16. (d) Dapporto, P.; Midollini, S.; Sacconi, L. Angew. Chem., Int. Ed. Engl. 1979, 18, 469.
17. (a) Ghilardi, C. A.; Sabatini, A.; Sacconi, L. Inorg. Chem. 1976, 15, 2763.
18. (b) Heydenrelch, F.; Mollback, A.; Wilke, G.; Dreeskamp, H.; Hoffmann, E. G.; Schroth, G.; Seevogel, K.; Stempfle, W. lsr. J. Chem. 1972, 10, 293.
19. P-H = 167 Hz, P(1)), 39 (m, 2P(2,3)), -133 (m, 2P, P(4,5)), -160 (m, 2P, P(6,7)).
20. P-H ≈ 14 Hz).
21. (a) Cook, C. D.; Wan, K. Y.; Gelius, U.; Hamrin, K.; Johansson, G.; Olsson, E.; Siegbahn, H.; Nordling, C.; Siegbahn, K. J. Am. Chem. Soc. 1971, 93, 1904.
22. (b) Cheng, P.-T.; Nyburg. S. C. Can. J. Chem. 1972, 50, 912.
23. (c) Glanville, J. O.; Stewart, J. M.; Grim, S. O. J. Organomet. Chem. 1967, 7, P9.
24. (d) Davies, B. W.; Payne, N. C. J. Organomei. Chem. 1975, 99, 315.
25. (e) Coordination of Unsaturated Molecules to Transiton Metals, Ittel, S., Ibers, J. A., Eds.; Academic Press: New York, 1976; Vol. 14, p 33.
26. Transition Metal Hydrides; Muetterties, E. L., Ed.; Marcel Dekker: New York, 1971.
27. Korber, N.; von Schnering, R G. J. Chem. Soc., Chem. Commun. 1995, 1713.