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Due to the low amount of the available sample, it was only possible to estimate an approximate value of ∈λmax ≈ 3600 for 1
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Due to the low amount of the available sample, it was only possible to estimate an approximate value of ∈λmax ≈ 3600 for 1.
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Water
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31
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15844424243
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note
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Molecular mechanics calculations, performed in our laboratory, for the intermolecular interactions between several simple (albeit with a noncoplanar B ring as is the case with the present set) anthocyanins and common copigments such as chlorogenic acid and caffeine, have demon-strated a preferential interaction between the B ring of the pigment and the aromatic residue(s) of the copigment.
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33
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37049085581
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34
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15844397671
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note
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35 of a simple polyhydroxylated anthocyanidin (3′,4′,3,7-tetrahydroxyflavylium) forming an hydrogen bond, through its 7-OH, with a malonate, produces a relative increase on the charge density of C-7 from 0.167 to 0.195, while the other free hydroxyl groups of the cation, notably the 4′-OH, remain almost unchanged.
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35
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0842341771
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Stewart, J.J.P.4
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