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2SO) are the same: this could be the case for bound triflate if spin delocalization to the fluorine atoms were negligible. In any case, a triflate-bound or solvated unique site is expected to be activated relative to the ethanethiolate-bound site in 4.
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39.51 which are indicative of π-delocalization of spin.
-
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96
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13344295733
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note
-
Because of large line widths of most resonances, percentages of species obtained by integration in tins and related experiments are semiquantitative only.
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97
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Carney, M J.; Papaefthymiou, G. C., Spartalian, K., Frankel, R. B., Holm, R H. J. Am Chem. Soc. 1988, 110, 6084 and references therein.
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100
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13344267053
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note
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4]0 clusters are being sought to examine the relationship between metric features and electronic structure.
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101
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105
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13344295734
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note
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2+ clusters typically absorb. For instance, a fit with free intensities to the spectrum of Figure 14B yields 31% and 69% for the intensities of site 1 and the sum of sites P2 and P3, respectively, rather than the expected 33 3% and 66.7%. While these differences could be attributed to different recoiless fractions of the sites, this interpretation would not explain the additional absorption in the "diamagnetic regions" of the high-field spectra.
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4 clusters may also suffice in this regard: (a) Whitener, M. A.; Peng, G.; Holm, R H. Inorg. Chem. 1991, 30, 2411. (b) Evans, D. J.; Garcia, G.; Leigh, G. J ; Newton, M. S.; Santana, M. D. J. Chem. Soc., Dalton Trans. 1992, 3229. (c) van Strijdonck, G. P. F.; van Haare, J. A. E. H.; van der Linden, J. G. M.; Steggerda, J. J , Nolte, R. J. M. Inorg. Chem. 1994, 33, 999.
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0342425066
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4 clusters may also suffice in this regard: (a) Whitener, M. A.; Peng, G.; Holm, R H. Inorg. Chem. 1991, 30, 2411. (b) Evans, D. J.; Garcia, G.; Leigh, G. J ; Newton, M. S.; Santana, M. D. J. Chem. Soc., Dalton Trans. 1992, 3229. (c) van Strijdonck, G. P. F.; van Haare, J. A. E. H.; van der Linden, J. G. M.; Steggerda, J. J , Nolte, R. J. M. Inorg. Chem. 1994, 33, 999.
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