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15
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85029984127
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note
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7 was the main reaction product. The manuscript relative to this study is presently under preparation.
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16
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85029998095
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note
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8
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17
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33751158919
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a) Chini, M.; Crotti, P.; Gardelli, C.; Macchia, F. J.Org.Chem. 1994, 59, 4131-4137.
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20
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37049171003
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a) Methyl β-glycoside 3 and its a anomer 15 (not shown) were prepared from commercially available 2-deoxy-D-ribose by a slight modification (see Experimental) of a previously described procedure: Deriaz, R.E.; Overend, W.G.; Stacey, M.; Wiggins, L.F. J.Chem.Soc. 1949, 2836-2841.
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0041797334
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b) For the physical data for compound 3, see: Inokawa, S.; Mitsuyoshi, T.; Kawamoto, H.; Yamamoto, H.; Yamashita, M. Carbohydr.Res. 1985, 142, 321-323.
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0001238829
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23
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0000119467
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b) Legters, J.; Thijs, L.; Zwanenburg, B. Tetrahedron Lett. 1989, 30, 4881-4884.
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24
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85030000615
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note
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6,7 of 13 in the complex mixture fraction from 12. However, if present, the regiosomeric C-4 product of 13 is present to an extent not superior to 5%.
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25
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85029997758
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note
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a axial).
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26
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0029005061
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Crotti, P.; Favero, L.; Gardelli, C.; Macchia, F.; Pineschi, M. J.Org.Chem. 1995, 60, 2514-2525.
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27
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85029997172
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note
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8,14
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28
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85029987355
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note
-
A preliminary attempt to prepare the amino sugar 2 directly by acid methanolysis (at 60°C) of the N-ethyl derivative of aziridine 11 (aziridine 16), was unsuccessful: the desired amino sugar 2 was formula presented obtained only in an unsatisfactory yield (55%) and in a mixture with another glycosidic product (45%) which, at that moment, was not further investigated (see Experimental).
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29
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85029983443
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note
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For the bicyclo-type nomenclature used in the case of aziridines 11 and 12, the numbering scheme is the following: formula presented
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30
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0001765832
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Kajimoto, T.; Liu, K.K.-C.; Pederson, R.L.; Zhong, Z.; Ichikawa, Y.; Porco, J.A.; Wong, C.-H. J .Am.Chem.Soc. 1991, 113, 6187-6196.
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31
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33845560339
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Kozikowski, A.P.; Ishida, H.; Isobe, K. J.Org.Chem. 1979, 44, 2788-2790.
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Kozikowski, A.P.1
Ishida, H.2
Isobe, K.3
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