13C-NMR study on the structure of isolated Sc2@C84 metallofullerene

Journal of the American Chemical Society

Volumn 118, Issue 9, 1996, Pages 2293-2294

  Yamamoto, Etsuji ^a   Tansho, Masataka ^a   Tomiyama, Tetsuo ^a   Shinohara, Hisanori ^a   Kawahara, Hironori ^b   Kobayashi, Yuji ^c  

^a NAGOYA UNIVERSITY   (Japan)

^b JEOL LTD   (Japan)

^c OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

FULLERENE DERIVATIVE; ORGANOMETALLIC COMPOUND;

ARTICLE; DRUG PURIFICATION; DRUG STRUCTURE; HIGH PERFORMANCE LIQUID CHROMATOGRAPHY; NUCLEAR MAGNETIC RESONANCE;

EID: 0029932130     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953393o     Document Type: Article

References (30)

1. Chai, Y.; Guo, T.; Jin, C.; Haufler, R. E.: Chibante, L. P. F.; Fure, J.; Wang, L.; Alford, J. M.; Smalley, R. E. J. Phys. Chem. 1991, 95, 7564.
2. Bethune, D. S.: Johnson, R. D.: Salem, J. R.; de Vries, M. S.; Yannoni, C. S. Nature 1993, 366, 123.
3. Alvarez, M, M.; Gillan, E. G.: Holczer, K.; Kaner, R. B.; Min. K. S.; Whenen, R. L. J. Phys. Chem. 1991, 95, 10561.
4. Johnson, R. D.; de Vries, M. S.; Salem, J.; Bethune, D. S.; Yannoni, C. S. Nature 1992, 355, 239.
5. Kikuchi, K.; Suzuki, S.; Nakao, Y.; Nakahara, N.; Wakabayashi, T.; Shiromaru, H.: Saito, I.; Ikemoto, I.; Achiba, Y. Chem. Phys. Len. 1993, 216, 67.
6. Weaver, J. H.; Chai, Y.; Kroll, G. H.; Jin, C.; Ohno, T. R.: Haufler, R. E.; Guo, T.; Alford, J. M.; Conceicao, J.: Chibante, L. P. F.; Jain, A.; Palmer, G.; Smalley, R. E. Chem. Phys. Lett. 1992, 190, 460.
7. Shinohara, H.; Sato, H.; Saito, Y.; Ohkohchi, M.; Ando, Y. J. Phys. Chem. 1992, 96, 3571.
8. Shinohara, H.; Sato, H.; Ohchochi, M.; Ando, Y.; Kodama, T.; Shida, T.; Kato, T.; Saito, Y. Nature 1992, 357, 52.
9. Shinohara, H.; Yamaguchi, H.; Hayashi, N.; Sato, H.; Inagaki, M.; Saito, Y.; Bandow, S.; Kitagawa, H.; Mitani, T.; Inokuchi, H. Mater. Sci. Eng. 1993, B19, 25.
10. Yannoni, C. S.; Hoinkis, M.; de Vries, M. S.; Bethune, D. S.; Salem, J. R.; Crowder, M. S.; Johnson, R. D. Science 1992, 256, 1191.
11. Gillan, E.; Yeretzian, C.; Min, K. S.; Alvarez, M. M.; Whetten, R. L.; Kaner, R. B. J. Phys. Chem. 1992, 96, 6869.
12. Moro, L.; Ruoff, R. S.; Becker, C. H.; Lorents, D. C.; Malhotra, R. J. Phys. Chem. 1993, 97, 6801.
13. Takata, M.; Umeda, B.; Nishibori, E.; Sakata, M.; Saito, Y.; Ohno, M.; Shinohara, H. Nature 1995, 377, 46.
14. Shinohara, H.; Yamaguchi, H.; Hayashi, N.; Sato, H.; Ohkohchi, M.; Ando, Y.; Saito, Y. J. Phys. Chem. 1993, 97, 4259.
15. Shinohara, H.; Hayashi, N.; Sato, H.; Saito, Y.; Wang, X. D.; Hashizume, T.; Sakurai, T. J. Phys. Chem. 1993, 97, 13438.
16. Beyers, R.; Kiang, C.-H.; Johnson, R. D.; Salem, J. R.; de Vries, M. S.; Yannoni, C. S.; Bethune, D. S.; Dorn, H. C.; Burbank, P.; Harich, K.; Stevenson, S. Nature 1994, 370, 196.
17. Kikuchi, K.; Nakao, Y.; Achiba, Y.; Nomura, M. In Recent Advances in the Chemistry and Physics of Fullerenes: Ruoff, R., Kadish, K., Eds.; ECS Inc.: San Francisco, 1995; Vol. I, pp 1300-1308.
18. Shelimov, K. B.; Jarrold, M. F. J. Am. Chem. Soc. 1995, 117, 6404.
19. Shinohara, H.; Takata, M.; Sakata, M.; Hashizume, T.; Sakurai, T. In Cluster-Assembled Solids: Sattler, K., Ed.; Transtech Pub.: Lebanon, NH, in press.
20. Shinohara, H.; Inakuma. M.; Hayashi, N.; Sato, H.; Saito, Y.; Kato, T.; Bandow, S. J. Phys. Chem. 1994, 98, 8597.
21. Shinohara, H.; Inakuma, M.; Kishida, M.; Yamazaki, S.; Hashizume, T.; Sakurai, T. J. Phys. Chem. 1995, 99, 13769.
22. 84(II) and -(III). were not separable by the Buckyclutcher I column but were separated by the Buckyprep column in the final HPLC stage.
23. 2@Cs4 were 38.6, 44.6. and 47.3 min at 30 °C. respectively.
24. In the three-stage separation, isomers I and II were also isolated as well as isomer III.
25. Observed line positions (ppm) (and relative intensities): 134.57 (2.3), 136.44 (2.1), 138.11 (2.2), 141.36(1.7), 143.14 (1.7), 143.18 (2.1), 143.49 (1.8), 144.67 (1.0), 146.19 (1.7), 146.99 (1.7), 147.73 (1.9).
26. Fowler, P. W.; Batten, R. C.; Monolopoulos, D. E. J. Chem. Soc., Faraday Trans. 1991, 87, 3103.
27. Fowler, P. W.; Manolopoulos, D. E. An Atlas of Fullerenes; Clarendon: Oxford, 1995: pp 258-259.
28. Kikuchi, K.; Nakahara, N.; Wakabayashi, T.; Suzuki, S.: Shiromaru, H.; Miyake, Y.; Saito, K.; Ikemoto, I.; Kainosho, M.; Achiba, Y. Nature 1992, 357, 142.
29. Nagase, S.; Kobayashi, K. Chem. Phys. Lett. 1994, 231, 319.
30. Takata, M.; Umeda, B.; Nishibori, E.; Sakata, M.; Yamamoto, E.; Shinohara, H. To be published.