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Compound 6 gave spectral data identical to that obtained for the product resulting from the addition of propionyl chloride to the complex 2 (see experimental section)
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Compound 6 gave spectral data identical to that obtained for the product resulting from the addition of propionyl chloride to the complex 2 (see experimental section).
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A six-membered early transition state was generally proposed for the exothermic allyltitanation reaction; see for example refs 2b and 4a
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A six-membered early transition state was generally proposed for the exothermic allyltitanation reaction; see for example refs 2b and 4a.
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25
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Because of the marked chemoselectivity of the allyltitanation reaction, several inert heteroatom bearing groups might also be introduced into a starting diene; see ref 2a and Reetz, M. T. Topics Cur. Chem. 1982, 106, 1.
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