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Volumn 37, Issue 23, 1996, Pages 3977-3980

Hydride reagents for stereoselective reductive amination. An improved preparation of 3-endo-tropanamine

Author keywords

[No Author keywords available]

Indexed keywords

3 TROPANAMINE; TROPANE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 0029897159     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)00760-5     Document Type: Article
Times cited : (27)

References (23)
  • 1
    • 85030198287 scopus 로고    scopus 로고
    • Summer intern participant in the Purdue University Quest Fellowship Program
    • Summer intern participant in the Purdue University Quest Fellowship Program.
  • 6
    • 85030209860 scopus 로고    scopus 로고
    • note
    • Ratios were obtained by capillary gas chromatography CAM Capillary column (15 m × 0.5 m I.D.). GC measurements were performed on a Hewlett-Packard 5200 GC instrument equipped with a flame ionization detector (FID) and a Hewlett-Packard electronic integrator. The carrier gas (helium) flow rate is 1 mL/rnin. with a 20:1 split ratio. The oven temperature is increased from 100°C to 220°C over 30 minutes.
  • 22
    • 85030198702 scopus 로고    scopus 로고
    • note
    • The reagent prepared from (±)-ethylhexanoic acid could also be a mixture of diastereomers.
  • 23
    • 85030200372 scopus 로고    scopus 로고
    • note
    • 4) and concentrated. The crude amine product was either hydrogenolyzed (5% Pd/C) to remove the benzyl group or isolated as an HCl salt by the addition of anhydrous HCl.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.