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85033863385
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note
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6): δ 2, 55.3; 3, 70.1; 4, 36.1; 5, 13.9; 6, -2.4; 7a,b, 46.3 and 37.0.
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29
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85033848633
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note
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Planarity at phosphorus in a phosphametallacyclobutene formulation seems unlikely, as orthogonality of the lone pair of electrons on phosphorus and the LUMO of the metallocene fragment precludes the stabilization of M-P multiple bonding.
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30
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0000102584
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85033833182
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note
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w: 5. 2495, 208,0.0799, 0.0668; 6, 1540, 248, 0.0777, 0.0634; 7, 2707, 229, 0.0953, 0.0761. Full details are deposited as supporting information.
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32
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85033833747
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note
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While we were able to determine that the rate of reaction did not depend on concentrations of either benzaldehyde or styrene oxide, rate constants have not been included due to unavoidable problems with decomposition in these reactions.
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