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Volumn 118, Issue 17, 1996, Pages 4204-4205

Synthesis and reactivity of phosphametallacyclobutenes: Sterically induced [4 + 2] retrocycloadditions

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOMETALLIC COMPOUND;

EID: 0029882681     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953470f     Document Type: Article
Times cited : (38)

References (34)
  • 28
    • 85033863385 scopus 로고    scopus 로고
    • note
    • 6): δ 2, 55.3; 3, 70.1; 4, 36.1; 5, 13.9; 6, -2.4; 7a,b, 46.3 and 37.0.
  • 29
    • 85033848633 scopus 로고    scopus 로고
    • note
    • Planarity at phosphorus in a phosphametallacyclobutene formulation seems unlikely, as orthogonality of the lone pair of electrons on phosphorus and the LUMO of the metallocene fragment precludes the stabilization of M-P multiple bonding.
  • 31
    • 85033833182 scopus 로고    scopus 로고
    • note
    • w: 5. 2495, 208,0.0799, 0.0668; 6, 1540, 248, 0.0777, 0.0634; 7, 2707, 229, 0.0953, 0.0761. Full details are deposited as supporting information.
  • 32
    • 85033833747 scopus 로고    scopus 로고
    • note
    • While we were able to determine that the rate of reaction did not depend on concentrations of either benzaldehyde or styrene oxide, rate constants have not been included due to unavoidable problems with decomposition in these reactions.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.