(1R, 2R)-2-nitroxycyclohexan-1-ol: First example of a cyclohexyl based chiral auxiliary with nitroxy function as diastereoface discriminating group

Tetrahedron Asymmetry

Volumn 7, Issue 4, 1996, Pages 997-1000

  Basavaiah, Deevi ^a   Pandiaraju, Subramanian ^a   Bakthadoss, Manickam ^a   Muthukumaran, Kannan ^a  

^a UNIVERSITY OF HYDERABAD   (India)

Author keywords

[No Author keywords available]

Indexed keywords

2 NITROCYCLOHEXAN 1 OL; CYCLOHEXANOL DERIVATIVE; NITRO DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHIRALITY; DRUG SYNTHESIS; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 0029879232     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/0957-4166(96)00101-2     Document Type: Article

References (17)

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14. 6 : C, 57.33; H, 5.15; N, 4.77 found C, 57.25, H, 5.17; N, 4.75.
15. 3) (50 MHz): 15.77, 16.95, 22.93, 23.22, 29.00, 29.74. 30.16, 35.22, 35.47. 73.41, 74.33, 80.88, 81.99, 125.62, 125.93, 127.64, 128.12, 140.70, 175.00 (the underlined chemical shift values are due to the minor diastereomer).
16. 3) (50 MHz) : δ 15.77, 17.27, 35.92, 81.10, 125.98, 127.86, 128.30, 140.41, 180.58.
17. Meyers, A.I.; Slade J., J. Org. Chem., 1980, 45, 2912-2914.