메뉴 건너뛰기




Volumn 52, Issue 14, 1996, Pages 4949-4962

Fullerenes by pyrolysis of hydrocarbons and synthesis of isomeric methanofullerenes

Author keywords

[No Author keywords available]

Indexed keywords

FULLERENE; FULLERENE DERIVATIVE; POLYCYCLIC HYDROCARBON;

EID: 0029874522     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(96)00103-2     Document Type: Article
Times cited : (60)

References (77)
  • 7
    • 0342548541 scopus 로고
    • Fullerenes: Synthesis, properties, and chemistry of large carbon clusters
    • Ed.: G.S. Hammond, V.J. Kuck
    • f) Heath, J. R. in Fullerenes: Synthesis, Properties, and Chemistry of Large Carbon Clusters (Ed.: G.S. Hammond, V.J. Kuck) (ACS Symp. Ser., No. 481, Washington D.C., 1991);
    • (1991) ACS Symp. Ser., No. 481, Washington D.C.
    • Heath, J.R.1
  • 15
    • 0001544825 scopus 로고
    • n) Grösser, T.; Hirsch, A.; Angew. Chem. 1993, 105, 1390-1392; Angew. Chem. Int. Ed. Engl. 1993, 32, 1340-1342;
    • (1993) Angew. Chem. , vol.105 , pp. 1390-1392
    • Grösser, T.1    Hirsch, A.2
  • 16
    • 33748222842 scopus 로고
    • n) Grösser, T.; Hirsch, A.; Angew. Chem. 1993, 105, 1390-1392; Angew. Chem. Int. Ed. Engl. 1993, 32, 1340-1342;
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 1340-1342
  • 23
    • 0038416399 scopus 로고
    • Schwarz, H. Angew. Chem. 1993, 105, 1475-1478; Angew. Chem. Int. Ed. Engl. 1993, 32, 1412-1415.
    • (1993) Angew. Chem. , vol.105 , pp. 1475-1478
    • Schwarz, H.1
  • 24
    • 33748248293 scopus 로고
    • Schwarz, H. Angew. Chem. 1993, 105, 1475-1478; Angew. Chem. Int. Ed. Engl. 1993, 32, 1412-1415.
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 1412-1415
  • 26
    • 33748235294 scopus 로고
    • Beiz, T.; Werner, H.; Zemlin, F.; Klengler, U.; Wesemann, M.; Tesche, B.; Zeitler, E.; Reller, A.; Schlögl, R. Angew. Chem. 1994, 106, 1919-1922; Angew. Chem. Int. Ed. Engl. 1994, 33, 1866-1869.
    • (1994) Angew. Chem. Int. Ed. Engl. , vol.33 , pp. 1866-1869
  • 27
    • 0001844585 scopus 로고
    • Curl, R. F. Nature 1994, 363, 14-15.
    • (1994) Nature , vol.363 , pp. 14-15
    • Curl, R.F.1
  • 38
    • 0342982921 scopus 로고
    • Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials
    • Taylor, R. T.; Langley, G. J. Proc. - Electrochem. Soc. 1994, 94-24, (Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials) 68-79.
    • (1994) Proc. - Electrochem. Soc. , vol.94 , Issue.24 , pp. 68-79
    • Taylor, R.T.1    Langley, G.J.2
  • 42
    • 85030195248 scopus 로고    scopus 로고
    • note
    • 60: 11.8 min.) was used with toluene/acetonitril 60:40 as eluent.
  • 43
    • 85030196605 scopus 로고    scopus 로고
    • note
    • 9 The yields of hydrocarbon pyrolyses in a pure Ar-atmosphere seem to be much lower.
  • 44
    • 85030192402 scopus 로고    scopus 로고
    • note
    • Fullerenes were only obtained, when freshly destilled cyclopentadiene was used. Starting with the dimer pyrolysis took place before the retro-Diels-Alder reaction.
  • 46
    • 85030195002 scopus 로고    scopus 로고
    • note
    • 82 (m/z = 984 u).
  • 47
    • 85030197122 scopus 로고    scopus 로고
    • note
    • 23
  • 50
    • 0001062417 scopus 로고
    • b) Hirsch, A. Angew. Chem. 1993, 105, 1189-1192; Angew. Chem. Int. Ed. Engl. 1993, 32, 1138.
    • (1993) Angew. Chem. , vol.105 , pp. 1189-1192
    • Hirsch, A.1
  • 51
    • 33749096786 scopus 로고
    • b) Hirsch, A. Angew. Chem. 1993, 105, 1189-1192; Angew. Chem. Int. Ed. Engl. 1993, 32, 1138.
    • (1993) Angew. Chem. Int. Ed. Engl. , vol.32 , pp. 1138
  • 56
    • 85030191152 scopus 로고    scopus 로고
    • note
    • For the symmetrically substituted methanofullerene 4 only four isomers are possible instead of six, because the isomers 4b and 4c respectively 4e and 4f are the same.
  • 65
    • 85030194248 scopus 로고    scopus 로고
    • note
    • 29,33,37
  • 67
    • 85030187883 scopus 로고    scopus 로고
    • note
    • 29
  • 68
    • 84988073214 scopus 로고
    • Stewart, J. J. P. QCPE # 455, MOPAC 6.0: PM3, RHF, closed shell, Grad = 0.2
    • Stewart, J. J. P. QCPE # 455, MOPAC 6.0: PM3, RHF, closed shell, Grad = 0.2; Stewart, J. J. P. J. Comp. Chem. 1989, 10, 221.
    • (1989) J. Comp. Chem. , vol.10 , pp. 221
    • Stewart, J.J.P.1
  • 70
    • 85030197362 scopus 로고    scopus 로고
    • note
    • f,r is calculated as the difference of the corresponding isomer and the stablest isomer.
  • 71
    • 85030194724 scopus 로고    scopus 로고
    • PhD thesis, Bonn, in preparation
    • Osterodt, J. PhD thesis, Bonn, in preparation.
    • Osterodt, J.1
  • 76
    • 85030188584 scopus 로고    scopus 로고
    • note
    • It is not possible to use larger amounts, since a silica tube with this diameter would be blocked then.
  • 77
    • 85030187763 scopus 로고    scopus 로고
    • note
    • Kroto and Taylor et al. first removed the acetone-soluble hydrocarbons, as fullerenes are nearly insoluble in acetone. But during our investigations we realised that in such low concentrations parts of the fullerenes are soluble in acetone: therefore we did not remove the acetone-soluble part.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.