The palladium-catalysed vinylic substitution of vinyl triflates with β-substituted-α,β-unsaturated carbonyl compounds. An application to the synthesis of cardenolides

Tetrahedron

Volumn 52, Issue 20, 1996, Pages 6983-6996

  Arcadi, Antonio ^a   Cacchi, Sandro ^b   Fabrizi, Giancarlo ^b   Marinelli, Fabio ^a   Pace, Paola ^b  

^a UNIVERSITY OF L'AQUILA   (Italy)

^b SAPIENZA UNIVERSITY OF ROME   (Italy)

Author keywords

[No Author keywords available]

Indexed keywords

CARDENOLIDE;

ARTICLE; DRUG SYNTHESIS; PRIORITY JOURNAL; REACTION ANALYSIS; STEREOCHEMISTRY; TECHNIQUE;

EID: 0029869371     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4020(96)00303-1     Document Type: Article

References (39)

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21. The relevant NOE effects for the determination of the regio- and stereochemistry of 3q and 3r, presented by arrows, are as follows: (formula presented) The same protons generated clear off-diagonal contours in NOESY spectra.
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29. 5
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31. 18 in the presence of tertiary amines have been used to prepare hydrovinylation derivatives from aryl halides and β-substituted-α,β-unsaturated carbonyl compounds.
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