The lifetime of formylcarbene determined by transient absorption and transient grating spectroscopy

Journal of the American Chemical Society

Volumn 118, Issue 14, 1996, Pages 3527-3528

  Toscano, John P ^a   Platz, Matthew S ^a   Nikolaev, Valerij ^b   Cao, Yanni ^c   Zimmt, Matthew B ^c  

^a OHIO STATE UNIVERSITY   (United States)

^b ST PETERSBURG STATE UNIVERSITY   (Russian Federation)

^c BROWN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

RADICAL;

ARTICLE; DRUG STABILITY; SPECTROPHOTOMETRY;

EID: 0029868337     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953810x     Document Type: Article

References (26)

1. Platz, M. S.; Maloney, V. M. Kinetics and Spectroscopy of Carbenes and Biradicals; Platz, M. S., Ed.; Plenum: New York, 1990; p 239.
2. Moss, R. A.; Turro, N. J. Kinetics and Spectroscopy of Carbenes and Biradicals; Platz, M. S., Ed.; Plenum: New York, 1990; p 213.
3. Platz, M. S.; Modarelli, D. A.; Morgan, S.; White, W. R.; Mullins, M., Celebi, S.; Toscano, J. P. Prog. React. Kinet. 1994, 19, 93.
4. (a) Toscano, J. P.; Platz, M. S.; Nikolaev, V.; Popic, V. J. Am. Chem. Soc. 1994, 116, 8146.
5. (b) Wang, J. L.; Toscano, J. P.; Platz, M. S., Nikolaev, V.; Popik, V. J. Am. Chem. Soc. 1995, 117, 5477.
6. (c) Toscano, J. P.; Platz, M. S., Nikolaev, V. J. Am. Chem. Soc. 1995, 117, 4712.
7. (d) It was not possible to saturate the yield of ylide in methylene chloride, thus, Stern-Volmer experiments were performed in Freon-113.
8. Jackson, J. E.; Platz, M. S. Advances in Carbene Chemistry; Vol. 1, Brinker, U., Ed., JAI Press: Greenwich, CT, 1994; Vol 1, p 89.
9. (a) Baron, W. J.; DeCamp, M. R.; Hendrick, M E.; Jones, M., Jr.; Levin, R. H.; Sohn, M. B. In Carbenes; Jones, M., Jr., Moss, R A., Eds.; Krieger: Malabar, FL, 1983; Vol. 1.
10. (b) Moss, R. A.; Jones, M., Jr. In Reactive Intermediates; Jones, M., Jr., Moss, R. A., Eds ; Wiley; New York. 1981, p 61.
11. (c) Moss, R. A , Jones, M., Jr. In Reactive Intermediates: Jones, M., Jr., Moss, R. A., Eds.; Wiley: New York, 1985; p 95.
12. (d) Marchand, A. P.; Brockway, N M. Chem. Rev. 1974, 74, 431.
13. (e) Kirsme, W. Carbene Chemistry, 2nd ed ; Academic Press: New York, 1978.
14. (f) Meier, H.; Zeller, K.-P. Angew. Chem., Int. Ed. Engl 1975, 14, 32.
15. (g) Torres, M.; Lown, E. M.; Gunning, H E.; Strausz, O. P. Pure Appl. Chem. 1980, 52, 1623
16. (h) Zeller, K.-P. Tetrahedron Lett. 1977, 707.
17. (i) Zeller, K.-P.; Meier, H.; Kolshor, H.; Muller, E. Chem. Ber. 1972, 105, 1875.
18. (j) Timm, U.; Zeller, K.-P.; Meier, H Tetrahedron 1977, 33, 453.
19. (a) Miller, R. J. D. In Advances in Spectroscopy, Clark, R J., Hester, R. E. Eds., John Wiley and Sons: New York, 1989; Vol. 18, p 1
20. (b) Morats, J.; Zimmt, M. B. J. Phys. Chem. 1995, 99, 8863
21. (c) Ma. J.; Dutt, B.; Waldeck, D. H.; Zimmt, M. B. J. Am. Chem. Soc 1994, 116, 10619.
22. (d) 74% of the detected expansion is prompt, the remaining 26% occurs with a time constant of 900 ps.
23. (a) Kaplan, F.; Meloy, G. K. J. Am. Chem. Soc. 1966, 88, 950.
24. (b) Kaplan, F., Mitchell, M. L. Tetrahedron Lett. 1979, 759.
25. (c) Arnold, Z. J. Chem. Soc., Chem. Commun. 1967, 299.
26. To our knowledge the quantum yield of disappearance of FDM is not known.