Role of van der Waals forces in enantioselective processes

Tetrahedron Letters

Volumn 37, Issue 15, 1996, Pages 2581-2584

  Mizutani, Tadashi ^a   Takagi, Hideki ^a   Ogoshi, Hisanobu ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANIC COMPOUND;

ARTICLE; ENANTIOMER; MOLECULAR DYNAMICS;

EID: 0029864924     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/0040-4039(96)00375-9     Document Type: Article

References (9)

1. For examples of chiral recognition, see (a) Kuroda, R.; Mason, S. F.; Rodger, C. D.; Seal, R. H. Mol. Phys. 1981, 42, 33.
2. (b) Schipper, P. E.; Harrowell, P. R. J. Am. Chem. Soc. 1983, 105, 723.
3. (c) Lipkowitz, K. B.; Demeter, D. A.; Parish, C. A.; Darden, T. Anal. Chem. 1987, 59, 1731.
4. For asymmetric synthesis, see. (a) Whitesell, J. K. Chem. Rev. 1989, 89, 1581.
5. (b) Arnett, E. M.; Harvey, N. G.; Rose, P. L. Acc. Chem. Res. 1989, 22, 131.
6. (c) Sawamura, M.; Ito, Y. Chem. Rev. 1992, 92, 857.
7. (d) Jones, D. K.; Liotta, D. C.; Shinkai, I.; Mathre, D. J. J. Org. Chem. 1993, 58, 799.
8. (d) Corey, E. J.; Sarshar, S.; Lee, D.-H. J. Am. Chem. Soc. 1994, 116, 12089.
9. o/2RT) x 100(%) if the entropy term is neglected. Similarly, that of 4 kcal/mol amounts to 99.7 %ee.