Oxidation of natural targets by dioxiranes. 4. High stereo- and regioselective conversion of vitamin D2 to its (all-R) tetraepoxide and C-25 hydroxy derivative

Journal of the American Chemical Society

Volumn 118, Issue 45, 1996, Pages 11089-11092

  Curci, Ruggero ^a   Detomaso, Antonia ^a   Lattanzio, Maria E ^a   Carpenter, Gene B ^b  

^a UNIVERSITY OF BARI   (Italy)

^b BROWN UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

VITAMIN D DERIVATIVE;

ARTICLE; DRUG SYNTHESIS; NUCLEAR MAGNETIC RESONANCE; OXIDATION; REACTION ANALYSIS; STEREOCHEMISTRY; TECHNIQUE;

EID: 0029862761     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9626300     Document Type: Article

References (27)

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3. For recent reviews on this now popular class of powerful oxidants, see: (a) Curci, R.; Dinoi, A.; Rubino, M. F. Pure Appl. Chem. 1995, 67, 811. (b) Adam, W.; Hadjiarapoglou, L. P.; Curci, R.; Mello, R. In Organic Peroxides; Ando, W., Ed.; Wiley: New York, 1992; Chapter 4, pp 195-219. See also references quoted therein.
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21. We thank a reviewer for the suggestion of this rationale.
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