Intramolecular model for the reductive acyl transfer catalyzed by α-keto acid dehydrogenases

Journal of the American Chemical Society

Volumn 118, Issue 45, 1996, Pages 11026-11029

  Chiu, Chingfan C ^a   Chung, Alex ^a   Barletta, Gabriel ^a   Jordan, Frank ^a  

^a RUTGERS UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

OXIDOREDUCTASE;

ARTICLE; ENZYME ACTIVITY; ENZYME MECHANISM; REACTION ANALYSIS;

EID: 0029860911     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja954322s     Document Type: Article

References (23)

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17. 2a either in our model or on the enzyme.
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20. This number is derived from the slopes of lines (4-3)/(2-1) (from the top) in Figure 1b.
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22. PDHc has many subunits and sufficient uncertainty about its precise stoichiometry, that comparison with these other ThDP-dependent decarboxylases may be more useful.
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