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Volumn , Issue 8, 1996, Pages 1002-1006

The Grignard reagent from 2-bromomethyl-1,3-dioxolane, a novel and efficient d2-reagent: Synthesis of branched chain carbohydrate derivatives

Author keywords

2 bromomethyl 1,3 dioxolane; carbohydrate ketones; d2 synthon; Grignard reagent; magnesium

Indexed keywords

CARBOHYDRATE DERIVATIVE;

EID: 0029834218     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1996-4321     Document Type: Article
Times cited : (17)

References (24)
  • 8
    • 0003129117 scopus 로고
    • Otto Salle Verlag: Frankfurt a. Main Berlin München
    • Seebach, D.; Hungerbühler, E. Modern Synthetic Methods, Vol. 2, Otto Salle Verlag: Frankfurt a. Main Berlin München, 1980, pp 91.
    • (1980) Modern Synthetic Methods , vol.2 , pp. 91
    • Seebach, D.1    Hungerbühler, E.2
  • 15
    • 9444238857 scopus 로고    scopus 로고
    • note
    • Using small amounts of ketones it was easier to work with 5-10 equiv of Grignard reagent 3.
  • 17
    • 9444240032 scopus 로고    scopus 로고
    • note
    • Assignment of configuration was achieved by NOE experiments: saturating 1′-H: 1-H 2.3%, saturating benzylidene-H: dioxolane-H 3.6%, compound 11; saturating 2′a-H and 2′b-H: 4-H 5%, compound 12; saturating H-6e: dioxolane-H 1.2%, compound 14.
  • 23
    • 0001510557 scopus 로고
    • 5,6 = 5.4 Hz; Lemieux, R. U.; Martin, C. J. Carbohydr. Res. 1970, 13, 139; Paulsen, H.; Redlich, H. Chem. Ber. 1974, 107, 2992.
    • (1970) Carbohydr. Res. , vol.13 , pp. 139
    • Lemieux, R.U.1    Martin, C.J.2
  • 24
    • 0016293765 scopus 로고
    • 5,6 = 5.4 Hz; Lemieux, R. U.; Martin, C. J. Carbohydr. Res. 1970, 13, 139; Paulsen, H.; Redlich, H. Chem. Ber. 1974, 107, 2992.
    • (1974) Chem. Ber. , vol.107 , pp. 2992
    • Paulsen, H.1    Redlich, H.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.