Macromolecule-like aspects for a colloidal suspension of an exfoliated titanate. Pairwise association of nanosheets and dynamic reassembling process initiated from it

Journal of the American Chemical Society

Volumn 118, Issue 35, 1996, Pages 8329-8335

  Sasaki, Takayoshi ^a   Watanabe, Mamoru ^a   Hashizume, Hideo ^a   Yamada, Hirohisa ^a   Nakazawa, Hiromoto ^a  

^a NATIONAL INSTITUTE FOR MATERIALS SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

METAL OXIDE;

ARTICLE; COMPUTER SIMULATION; DRUG STRUCTURE; MOLECULAR DYNAMICS; REACTION ANALYSIS; THEORY;

EID: 0029833269     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja960073b     Document Type: Article

References (71)

1. Jacobson, A. J. Mater. Sci. Forum 1994, 152-153, 1-12.
2. Alberti, G.; Casciola, M.; Costantino, U. J. Colloid Interface Sci. 1985, 107, 256-263.
3. Divigalpitiya, W. M. R.; Frindt, R. F.; Morrison, S. R. Science 1989, 246, 369-371.
4. Miremadi, B. K.; Morrison, S. R. J. Appl. Phys. 1990, 67, 1515-1520.
5. Nazar, L. F.; Liblong, S. W.; Yin, X. T. J. Am. Chem. Soc. 1991, 113, 5889-5890.
6. Divigalpitiya, W. M. R.; Frindt, R. F.; Morrison, S. R. J. Mater. Res. 1991, 6, 1103-1107.
7. Kanatzidis, M. G.; Bissessur, R.; DeGroot, D. C.; Schindler, J. L.; Kannewurf, C. R. Chem. Mater. 1993, 5, 595-596.
8. Lemmon, J. P.; Lerner, M. M. Chem. Mater. 1994, 6, 207-210.
9. Guay, D.; Divigalpitiya, W. M. R.; Belanger, D.; Feng, X. H. Chem. Mater. 1994, 6, 614-619.
10. (a) Manivannan, A.; Santiago, Y.; Cabrera, C. R. J. Vac. Sci. Technol. B 1994, 12, 2111-2114.
11. (b) Santiago, Y.; Cabrera, C. R. J. Electrochem. Soc. 1994, 141, 629-635.
12. Yang, D.; Frindt, R. F. Mol. Cryst. Liq. Cryst. 1994, 244, 355-360.
13. Foglia, S.; Tomlinson, A. A. G.; Mulley, S.; Sironi, A. J. Mater. Chem. 1995, 5, 1191-1196.
14. Kleinfield, E. R.; Ferguson, G. S. Science 1994, 265, 370-373.
15. Keller, S. W.; Kim, H.-N.; Mallouk, T. E. J. Am. Chem. Soc. 1994, 116, 8817-8818.
16. (a) Nadeau, P. H.; Wilson, M. J.; McHardy, W. J.; Tait, J. M. Science 1984, 225, 923-925.
17. (b) Nadeau, P. H.; Wilson, M. J.; McHardy, W. J.; Tait, J. M. Clay Miner. 1984, 19, 67-76.
18. (c) Nadeau, P. H.; Wilson, M. J.; McHardy, W. J.; Tait, J. M. Clay Miner. 1984, 19, 757-769.
19. Bonneau, P.; Mansot, J. L.; Rouxel, J. Mater. Res. Bull. 1993, 28, 757-766.
20. Treacy, M. M. J.; Rice, S. B.; Jacobson, A. J.; Lewandowski, J. T. Chem. Mater. 1990, 2, 279-286.
21. (a) Liu, C.; Singh, O.; Joensen, P.; Curzon, A. E.; Frindt, R. F. Thin Solid Films 1984, 113, 165-172.
22. (b) Joensen, P.; Frindt, R. F.; Morrison, S. R. Mater. Res. Bull. 1986, 21, 457-461.
23. (c) Joensen, P.; Crozier, E. D.; Alberding, N.; Frindt, R. F. J. Phys. C: Solid State Phys. 1987, 20, 4043-4053.
24. (d) Yang, D.; Jiménez Sandoval, S.; Divigalpitiya, W. M. R.; Irwin, J. C.; Frindt, R. F. Phys. Rev. B 1991, 43, 12053-12056.
25. (a) Izawa, H.; Kikkawa, S.; Koizumi, M. J. Phys. Chem. 1982, 86, 5023-5026.
26. (b) Feist, T. P.; Mocarski, S. J.; Davies, P. K.; Jacobson, A. J.; Lewandowski, J. T. Solid State Ionics 1988, 28-30, 1338-1343.
27. (c) Feist, T. P.; Davies, P. K. J. Solid State Chem. 1992, 101, 275-295.
28. (a) Marchand, R.; Brohan, L.; Tournoux, M. Mater. Res. Bull. 1980, 15, 1129-1133.
29. (b) Sasaki, T.; Watanabe, M.; Komatsu, Y.; Fujiki, Y. Inorg. Chem. 1985, 24, 2265-2271.
30. Sasaki, T.; Komatsu, Y.; Fujiki, Y. Chem. Mater. 1992, 4, 894-899.
31. (a) Sasaki, T.; Komatsu, Y.; Fujiki, Y. J. Chem. Soc., Chem. Commun. 1991, 817-818.
32. (b) Sasaki, T.; Watanabe, M.; Michiue, Y.; Komatsu, Y.; Izumi, F.; Takenouchi, S. Chem. Mater. 1995, 7, 1001-1007.
33. (a) Izawa, H.; Kikkawa, S.; Koizumi, M. J. Solid State Chem. 1985, 60, 264-267.
34. (b) Izawa, H.; Kikkawa, S.; Koizumi, M. J. Solid State Chem. 1987, 69, 336-342.
35. (a) Sasaki, T.; Watanabe, M.; Komatsu, Y.; Fujiki, Y. Bull. Chem. Soc. Jpn. 1985, 58, 3500-3505.
36. (b) Sasaki, T.; Komatsu, Y.; Fujiki, Y. Mater. Res. Bull. 1987, 22, 1321-1328.
37. (c) Sasaki, T.; Komatsu, Y.; Fujiki, Y. Inorg. Chem. 1989, 28, 2776-2779.
38. (a) Anderson, M. W.; Klinowski, J. Inorg. Chem. 1990, 29, 3260-3263.
39. (b) Landis, M. E.; Aufdembrink, B. A.; Chu, P.; Johnson, I. D.; Kirker, G. W.; Rubin, M. K. J. Am. Chem. Soc. 1991, 113, 3189-3190.
40. (a) Cheng, S.; Wang, T. Inorg. Chem. 1989, 28, 1283-1289.
41. (b) Sylvester, P.; Cahill, R.; Clearfield, A. Chem. Mater. 1994, 6, 1890-1898.
42. (c) Hou, W.; Van, Q.; Peng, B.; Fu, X. J. Mater. Chem. 1995, 5, 109-114.
43. Izawa, H.; Kikkawa, S.; Koizumi, M. Polyhedron 1983, 2, 741-744.
44. (a) Clément, P.; Marchand, R. C. R. Acad. Sci. Paris Ser. 11 1983, 296, 1161-1164.
45. (b) Miyata, H.; Sugahara, Y.; Kuroda, K.; Kato, C. J. Chem. Soc., Faraday Trans. 1 1988, 84, 2677-2682.
46. Sasaki, T.; Izumi, F.; Watanabe, M. Chem. Mater. 1996, 8, 777-782.
47. We use this term "nanosheet" for the individual host layers, the thickness of which is approximately 0.75 nm (see Figure 1). The lateral dimension was in a range of 0.3-1.0 μm for the material used in this study, which should be dependent on preparation modes of the parent Cs compound.
48. Although the 010 line was not visible at this stage being buried in a tail of the direct beam, it became perceptible as the intersheet distance contracted (see Figure 5).
49. International Tables for X-ray Crystallography; The International Union of Crystallography, The Kynoch Press: Birmingham, England, 1968; pp 201-207.
50. W))/(2π·sinθ/λ)
51. The contribution from TBA ion is negligibly small because of its small scattering power, similar to that of water, and its low population in comparison with the number of water molecules.
52. Cullity, B. D. Elements of X-ray Diffraction: Addison-Wesley Publishing Company, Inc.: Reading, MA, 1957.
53. There is some hysteresis between drying and rehydration processes.
54. The XRD data (Figure 2c) were recorded for the sample in filmlike texture as a result of the drying of the aggregate, in which h*l reflections were suppressed due to preferred orientation. They were enhanced considerably for a well-ground sample.
55. The increment of the stacking number was not discrete but continuous. For example, there was not an explicit transition point along the time evolution curve (Figure 6a) where the fit changes in an obvious way from the pairwise assembly to three-sheet species. This may be explained by a mixture of a lower aggregate and higher ones the proportion of which changes steadily.
56. (a) MacEwan, D. M. C.; Wilson, M. J. Crystal Structures of Clay Minerals and Their X-Ray Identification; Brindley, G. W., Brown, G., Eds.; Mineralogical Society: London, 1980; pp 206-211.
57. (b) Glaeser, R.; Méring, J. C. R Hebd. Séances Acad. Sci., Paris 1968, 267, 436-466.
58. (c) Moore, C. M.; Hower, J. Clays Clay Miner. 1986, 34, 379-384.
59. (d) Watanabe, T.; Sato, T. Clay Sci. 1988, 7, 129-138.
60. (e) Yamada, H.; Nakazawa, H.; Hashizume, H.; Shimomura, S.; Watanabe, T. Clays Clay Miner. 1994, 42, 77-80.
61. Schöllhorn, R. Intercalation Chemistry; Whittingham, M. S., Jacobson, A. J., Eds.; Academic Press: New York, 1982.
62. Although several classes of layered compounds have been reported to undergo delamination to single sheets, or infinite swelling, organized hydrated structures with exceptionally high degree of expansion have not been found except for clay minerals and the present material.
63. (a) Norrish, K. Discuss. Faraday Soc. 1954, 18, 120-134.
64. (b) Foster, W. R.; Savins, J. E.; Waite, J. M. Clays Clay Miner. 1955, 3, 296-316.
65. (c) Fukushima, Y. Clays Clay Miner. 1984, 32, 320-326.
66. Güven, N. Hydrous Phyllosilicates; Bailey, S. W., Ed.; Mineralogical Society of America: Washington, DC, 1988.
67. Rouxel, J. Chim. Scr. 1988, 28, 33-40.
68. Stein, A.; Keller, S. W.; Mallouk, T. E. Science 1993, 259, 1558-1564.
69. (a) Hervieu, M.; Raveau, B. Rev. Chim. Min. 1981, 18, 642-649.
70. (b) Grey, I. E.; Madsen, I. C.; Watts, J. A.; Bursill, L. A.; Kwiatkowska, J. J. Solid State Chem. 1985, 58, 350-356.
71. (c) Grey, I. E.; Li, C.; Madsen, I. C.; Watts, J. A. J. Solid State Chem. 1987, 66, 7-19.