Saponins from alfalfa, clover, and mungbeans analyzed by electrospray ionization-mass spectrometry as compared with positive and negative FAB-mass spectrometry

Advances in Experimental Medicine and Biology

Volumn 405, Issue , 1996, Pages 353-364

  Lee, M K ^a   Ling, Y C ^a   Jurzysta, M ^b   Waller, G R ^c  

^a NATIONAL TSING HUA UNIVERSITY   (Taiwan)

^b STATE RESEARCH INSTITUTE   (Poland)

^c OKLAHOMA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

SAPONIN; SOYASAPONIN I;

ALFALFA; BEAN; CHEMICAL STRUCTURE; CONFERENCE PAPER; EXTRACTION; MASS SPECTROMETRY; PLANT ROOT; PLANT SEED; PRIORITY JOURNAL;

MEDICAGO SATIVA; PHASEOLUS (ANGIOSPERM); TRIFOLIUM;

EID: 0029824095     PISSN: 00652598     EISSN: None     Source Type: Book Series    
DOI: 10.1007/978-1-4613-0413-5_30     Document Type: Conference Paper

References (12)

1. H.J. Budzikiewicz, C. Djerassi, and D.H. Williams, Structure Elucidation of Natural Products by Mass Spectrometry, Holden-Day, San Francisco, Vol. 2, pp 204-240 (1964).
2. K. Hostettmann, J. Doumas, and M. Hardy, Desorption/chemical ionization mass spectrometry of naturally occurring glycosides, Helv. Chim. Acta, 64: 297 (1981).
3. H.-R. Schulten, T. Soldati, T. Kawasaki, T. Okuyama, and S. Shibata, Confirmation of new, high-mass saponins from Gleditsia japonica by field desorption mass spectrometry, Planta Med. 46: 67 (1982).
4. K.R. Price, J. Eagles, and G.R. Fenwick, Saponin composition of 13 varieties of legume seeds using fast atom bombardment mass spectrometry, J. Sci. Food Agric. 42: 183 (1988).
5. P.R. West, P.W. Geno, G.R. Waller, W. Oleszek, and M. Jurzysta, Liquid secondary ion mass spectrometry and linked scanning at constant B/E LSIMS/MS for structure confirmation of saponins in Medicago sativa (alfalfa), InSaponins Used in Food and Agriculture, G.R. Waller and K. Yamasaki, eds., Plenum Publishing Co., New York, NY. In press, 1996.
6. G.R. Waller, M. Jurzysta, and R.L.Z. Thorne, Root saponins from alfalfa (Medicago sativa L.) and their allelopathic activity on weeds and wheat, Allelopathy J. 2: 21 (1995).
7. R.M. Facino, M. Carini, P. Traldi, B. Belli, B. Gioia, and E. Arlandini, Confirmatory assay and quantitative determination of Hedera helix L. saponins (α-hederin, hederacosides B and C) in raw plant extracts and in cosmetic formulations by EI and CAD MIKES spectrometry, Biomed. Environ. Mass Spectrom. 14: 187 (1987).
8. M.P. Maillard and K. Hostettmann, Determination of saponins in crude plant extracts by liquid chromatography-thermospray mass spectrometry, J. Chromatogr. 647: 137 (1993).
9. C.E. Costello, Application of tandem mass spectrometry spectral approaches to sturctural determinations of saponins, InSaponins Used in Food and Agriculture, G.R. Waller and K. Yamasaki, eds., Plenum Publishing Co., New York, NY. In press, 1996.
10. K. Hostettman, Search for mulluscicidal and antifungal saponins from tropical plants, InSaponins Used in Traditional and Modern Medicine, G.R. Waller and K. Yamasaki, eds., Plenum Publishing Co., New York, NY. In press, 1996.
11. M. Jurzysta, K.R. Price, C. Ridout, and R. Fenwick, The structures of four triterpenoid saponins isolated from the seed of Trifolium incarnatum L., Acta Soc. Bot. Pol. 58: 575 (1989).
12. M.K. Lee, Y.C. Ling, P.J. Huang, and S.M. Wang, Ionization efficiency of dicopper complex in electrospray ionization mass spectrometry, J. Chin. Chem. Soc. 41: 711 (1994)